Enhanced dielectrical and mechanical properties of polypropylene/ poly (vinylidene fluoride) blends with chlorinated polyethylene

C. Li, Jiang Wang, Guliang Fu
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Abstract

In this paper, polypropylene and poly (vinylidene fluoride) (PVDF) was Melt blended and the effect of chlorinated polyethylene (CPE) as compatibilizer was studied. CPE was effective in compatibilizing the component of PP and PVDF. The addition of CPE improved the crystallization of PVDF component through promoting its crystallization speed, increasing the crystallization temperature and crystallization degree. The improvement in the morphology and structure of the samples by CPE results in the increase in tensile strength and storage modulus of the prepared samples. The increase in tensile strength is 11 % (the elongation at break is also increased a little) at 6 wt%CPE loading. Besides, the increase in dielectric permittivity at 103 Hz are 9.0% and 12 % for the systems containing 6 wt% and 10 wt% CPE, respectively, which makes the prepared samples more attractive in application.
氯化聚乙烯增强聚丙烯/聚偏氟乙烯共混物的介电性能和机械性能
对聚丙烯和聚偏氟乙烯(PVDF)进行了熔融共混,研究了氯化聚乙烯(CPE)作为增容剂的作用。CPE对PP和PVDF组分有较好的相容性。CPE的加入促进了PVDF组分的结晶速度,提高了结晶温度和结晶程度,从而改善了PVDF组分的结晶。CPE改善了样品的形貌和结构,提高了制备样品的抗拉强度和存储模量。在6 wt%的CPE载荷下,拉伸强度增加11%(断裂伸长率也略有增加)。此外,当CPE含量为6 wt%和10 wt%时,103hz时的介电常数分别增加了9.0%和12%,这使得制备的样品更具应用吸引力。
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