New high conductivity lead (Pb)-free conducting adhesives

S.K. Kang, T. Graham, S. Purushothaman, J. Roldan, R. Saraf
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引用次数: 8

Abstract

Solder interconnection technology is currently in need of alternatives to address environmental issues associated with lead (Pb) abatement, and elimination of fluxes and flux cleaning solvents, and technical challenges related to extending to fine pitch assembly. Electrically conducting adhesive technology is one of the alternatives being actively considered in this context. The most common conductive adhesive used today is an epoxy resin filled with fine silver particles. Silver particles provide electrical conduction, while epoxy provides adhesive bonding of the components to a substrate. This material has several limitations such as low electrical conductivity, low joint strength, increase in contact resistance upon thermal cycling, and silver migration. In order to overcome these limitations, a new formulation is proposed based on alternative Pb-free conducting filler powders and tailored polymer resins. This new material provides a metallurgical bonding as well as polymer adhesive bonding leading to an increase in joint strength and in electrical conductivity. Several potential applications of these adhesive materials such as glass-to-board connection in LCD packaging, SMT package assembly to PCB, and direct chip attachment to a high density card are discussed.
新型高导电性无铅导电胶
焊料互连技术目前需要替代方案来解决与铅(Pb)减排、消除助焊剂和助焊剂清洁溶剂相关的环境问题,以及与扩展到细间距组装相关的技术挑战。导电胶粘剂技术是目前正在积极考虑的替代技术之一。目前最常用的导电胶粘剂是填充有细银颗粒的环氧树脂。银颗粒提供导电性,而环氧树脂提供组件与衬底的粘合剂粘合。这种材料有几个局限性,如低导电性,低接头强度,热循环时接触电阻增加,银迁移。为了克服这些限制,提出了一种基于替代无铅导电填料粉末和定制聚合物树脂的新配方。这种新材料提供了冶金粘合以及聚合物粘合剂粘合,从而增加了接头强度和导电性。讨论了这些粘合材料的几种潜在应用,如LCD封装中的玻璃到板连接,SMT封装组装到PCB,以及高密度卡的直接芯片连接。
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