III-V compound semiconductor nanowires for optoelectronic applications

Q. Gap, H. Joyce, Y. Kim, H. Tan, C. Jagadish, H. Wang, Y. Guo, J. Zou
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Abstract

Summary form only given. In the last few years, semiconductor nanowires (NWs) have attracted intensive attention due to both the intriguing fundamental properties and their potential applications in optoelectronic devices. GaAs NWs grown by metalorganic chemical vapor deposition (MOCVD) often exhibit tapered and kinked morphologies, depending on growth temperature. However, straight NWs of uniform diameter are preferred for device applications. We have developed a two-temperature growth procedure using MOCVD to simultaneously minimize adatom diffusion, tapering and kinking. GaAs NWs grown by this procedure have shown no planar defects and smooth sidewalls. This procedure should enable the development of ternary NWs with uniform composition and shape. Compared with a large amount of studies on GaAs, InP and GaN based III-V NWs, the antimonide III-V NWs have received little attention, despite their great potential for near- and mid-infrared device applications. Recently, GaSb subwavelength-wire lasers emitting near 1.55 mum have been demonstrated which opened the possibility to use NWs for telecommunications. In this talk, we report a successful growth of GaSb/GaAs heterostructure NWs on GaAs (111) B substrate by MOCVD. No misfit dislocations can be observed in the GaSb NW part from HRTEM, which suggests a complete strain relaxation of the GaSb NW on the GaAs NW.
光电应用的III-V型化合物半导体纳米线
只提供摘要形式。近年来,半导体纳米线因其独特的基本特性和在光电器件中的潜在应用而受到广泛关注。通过金属有机化学气相沉积(MOCVD)生长的GaAs NWs通常表现出锥形和弯曲的形貌,这取决于生长温度。然而,对于器件应用来说,直径均匀的直NWs是首选。我们已经开发了一种使用MOCVD的双温生长程序,以同时减少吸附原子扩散,变细和缠绕。用这种方法生长的砷化镓纳米墙没有平面缺陷,侧壁光滑。这一过程应该能够开发出具有均匀成分和形状的三元NWs。与基于GaAs, InP和GaN的III-V NWs的大量研究相比,尽管锑化物III-V NWs在近红外和中红外器件应用方面具有很大的潜力,但却很少受到关注。最近,发射近1.55 μ m的GaSb亚波长线激光器已被证明,这为将NWs用于电信开辟了可能性。在这次演讲中,我们报道了利用MOCVD在GaAs (111) B衬底上成功生长GaSb/GaAs异质结构NWs。在GaAs NW上未观察到错配位错,表明GaAs NW在GaAs NW上发生了完全的应变松弛。
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