PHOTOCATALYTIC DEGRADATION OF BISPHENOL E WITH NANO-SCLAED TiO2 IN AQUEOUS SOLUTION UNDER SOLAR RADIATION

Tomoki Sugiyama, A. Dabwan, M. Furukawa, Ikki Tateishi, H. Katsumata, S. Kaneco
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Abstract

In this work focus was paid to the photocatalytic degradation of Bisphenol E with nano-scaled TiO2 solution under sunlight. Instruments used for characterization and study the removal efficiency were; visible ultraviolet spectrophotometer, SEM (acceleration voltage 25kV) and TEM (acceleration voltage 80kV), X-ray diffraction and BET surface area. Under the optimum conditions; (pH;6, Radiation time; 90 min, Catalyst wt; 0.2g, reaction temperature; 20 oC), complete degradation was obtained. Byproducts from this study could be similar to our previous ones since Bisphenol A and Bisphenol E have very similar structures, hence their decomposition intermediates most probable not to be far. it was found that the decomposition reaction of bisphenol E follows the pseudo-first-order reaction kinetics
太阳辐射下纳米TiO2光催化降解水溶液中的双酚E
本文主要研究了纳米TiO2溶液在日光下光催化降解双酚E。用于表征和研究去除率的仪器有;可见紫外分光光度计,扫描电镜(加速电压25kV)和透射电镜(加速电压80kV), x射线衍射和BET比表面积。在最佳条件下;6、辐射时间;90分钟,催化剂wt;0.2g,反应温度;20℃),得到完全降解。由于双酚A和双酚E具有非常相似的结构,因此本研究的副产物可能与我们之前的产物相似,因此它们的分解中间体很可能离我们不远。发现双酚E的分解反应符合准一级反应动力学
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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