Evaluation of Styrene Content over Physical and Chemical Properties of Elastomer/TPS-EVOH/Chicken Feather Composites

M. Méndez-Hernández, J. Rivera‐Armenta, ZahidaSandoval-Arellano, B. Salazar-Cruz, María YolandaChavez-Cinco
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引用次数: 7

Abstract

A series of styrene-butadiene (SB) elastomer/thermoplastic starch (TPS)/ethylene vinyl alcohol copolymer (EVOH) composites were modified including chicken feathers in its formulation, which have the main component keratin. The composites were prepared by means of melt blending, and their chemical interactions were evaluated by means of infrared spectroscopy (FTIR), and their thermal properties as Tg values were investigated using differential scanning calorimetry (DSC), thermal stability using thermogravimetric analysis (TGA), and viscoelastic properties with dynamic mechanical analysis (DMA). The styrene content in SB was changed in 3 levels, and chicken feather content also changed in 3 levels . It was identified that Tg value in composites decreases that is attrib - uted to the styrene content in elastomer and that the chicken feather improved the stor age modulus of composite. The thermal stability of composites also was affected by the presence of chicken feathers due its good thermal properties.
苯乙烯含量对弹性体/TPS-EVOH/鸡毛复合材料理化性能的影响
以鸡毛为主要成分,以角蛋白为主要组分,对丁二烯弹性体(SB) /热塑性淀粉(TPS)/乙烯醇共聚物(EVOH)复合材料进行改性。采用熔融共混法制备了复合材料,利用红外光谱(FTIR)评价了复合材料的化学相互作用,用差示扫描量热法(DSC)研究了复合材料的热性能(Tg),用热重分析(TGA)研究了复合材料的热稳定性,用动态力学分析(DMA)研究了复合材料的粘弹性。SB中苯乙烯含量变化了3个水平,鸡毛含量也发生了3个水平的变化。结果表明,复合材料的Tg值降低与弹性体中苯乙烯含量的增加有关,鸡毛的加入提高了复合材料的储存模量。鸡毛的存在也影响了复合材料的热稳定性,因为鸡毛具有良好的热性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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