Electrochemical Impedance Spectroscopy Processing and Modelling for Lithium-ion Batteries Using Python and Jupiter

Martin Molhanec, V. Knap
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Abstract

This paper describes how to model a Lithium-ion battery’s internal characteristics based on electrochemical impedance spectroscopy (EIS) data and their fitting into an Equivalent Circuit Model (ECM) using Python and the Jupyter development environment. The described method is used on an extensive dataset collected during an ageing campaign of lithium-ion batteries. The work aims to determine the correct values of ECM elements with satisfactory accuracy. The battery’s ECM parameter interpretation provides essential information about its internal structure and mechanisms, which helps to understand its processes and estimate its future degradation. It was necessary to deal with two tasks: first, the processing of many measurements, and second, estimating the appropriate input parameters for the ECM. We have managed to practically automate the processing of more than one thousand files with measured data and design and gradually refine a method for estimating input parameters for ECM fitting.
使用Python和Jupiter进行锂离子电池的电化学阻抗谱处理和建模
本文介绍了如何利用Python和Jupyter开发环境,基于电化学阻抗谱(EIS)数据对锂离子电池内部特性进行建模,并将其拟合到等效电路模型(ECM)中。所描述的方法用于在锂离子电池老化运动期间收集的广泛数据集。本工作的目的是在满意的精度下确定ECM元素的正确值。电池的ECM参数解释提供了有关其内部结构和机制的基本信息,有助于了解其过程并估计其未来的退化。有必要处理两项任务:第一,处理许多测量,第二,估计ECM的适当输入参数。我们已经成功地实现了对超过1000个测量数据和设计文件的自动化处理,并逐步完善了一种估计ECM拟合输入参数的方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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