Optical properties of BxInyGa1-x-yAs/GaAs grown by Metal Organic Chemical Vapor deposition for solar cell

R. Hamila, F. Saidi, H. Maaref, P. Rodriguez, L. Auvray, Y. Monteil
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Abstract

The present invention further includes a method for substantially lattice matching single-crystal III–V semiconductor layers by including boron in the chemical structure of active cells layers in multi-junction solar. Solar photovoltaic devices, i.e., solar cells, are devices capable of converting solar radiation into usable electrical energy. The energy conversion occurs as the photovoltaic-effect which occurs in a cell composed of a p-type semiconductor layer adjacent to an n-type semiconductor layer, here after referred to as p-n junction cell. Solar radiation impinging on a solar cell and absorbed by active region of semiconductor material generates electricity. Therefore, a quaternary material III–V semiconductor BInGaAs has been tested for the application in solar cells [1]. Single layer has been grown lattice matched on GaAs using Metal Organic Chemical Vapor deposition (MOCVD). Optical study has been achieved of B0.0108In0.36Ga0.062As quantum well. At room temperature (300 K) PL study has shown an asymmetric PL band is around 1.19 eV of the emission energies. Based in these experimental results, we have suggested that the band gap energies of BInGaAs QW could be adequate for active cells layers in multijunction solar.
金属有机化学气相沉积法生长BxInyGa1-x-yAs/GaAs的光学性质
本发明还包括一种通过在多结太阳能电池活性电池层的化学结构中加入硼来实现基本晶格匹配单晶III-V半导体层的方法。太阳能光伏装置,即太阳能电池,是能够将太阳辐射转化为可用电能的装置。能量转换以光伏效应的形式发生,这种光伏效应发生在由相邻的p型半导体层组成的电池中,下文称为p-n结电池。太阳辐射冲击到太阳能电池上,被半导体材料的有源区吸收后产生电能。因此,一种四元材料III-V半导体BInGaAs已被测试用于太阳能电池[1]。利用金属有机化学气相沉积(MOCVD)技术在砷化镓表面生长出晶格匹配的单层薄膜。实现了B0.0108In0.36Ga0.062As量子阱的光学研究。在室温下(300 K)的PL研究表明,不对称的PL波段约为1.19 eV的发射能量。基于这些实验结果,我们认为BInGaAs QW的带隙能量可以满足多结太阳能有源电池层的需要。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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