OBTAINING ZINC OXIDE NANORODS BY HYDROTHERMAL METHOD

B. Seitov, A. Kazbek
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Abstract

Thin films of zinc oxide (ZnO) are very promising for thin-film transistors, solar panels, sensors and optoelectronic devices. The article presents the structural properties and morphology of zinc oxide (ZnO) obtained by hydrothermal synthesis. ZnO nanofilms (as a seed layer) were deposited by the sol-gel method on the glass surface of STO. The results of the experiment showed that the concentration of chemical reagents in the process of sol-gel transformation has a strong effect on the properties of ZnO films. Samples of ZnO nanorods on the surface of the nanofilm were obtained by hydrothermal method at a solution temperature of about 97 ° C for 3 hours.After firing the synthesized ZnO nanorods, the electrical resistance increased several times. The chemical composition and morphology of the obtained nanorods arrays were characterized by scanning electron microscopy and X-ray diffraction. As a result of the study, arrays of ZnO nanoparticles showed a highly improved response to visible light. The results of the article can be used in other combinations of metal oxides, and also offer many interesting opportunities for further development of high-performance photoelectrochemical devices for solar energy conversion. The results of scientific research are the most important material data for alternative energy and can be used by industry specialists in the creation of photoelectrochemical systems for generating hydrogen fuel with the formation of active photanode layers of water decomposition systems with zinc oxide.
水热法制备氧化锌纳米棒
氧化锌薄膜在薄膜晶体管、太阳能电池板、传感器和光电子器件等领域具有广阔的应用前景。介绍了水热合成氧化锌(ZnO)的结构性质和形貌。采用溶胶-凝胶法在STO玻璃表面沉积ZnO纳米膜(作为种子层)。实验结果表明,溶胶-凝胶转化过程中化学试剂的浓度对ZnO薄膜的性能有很强的影响。采用水热法制备纳米膜表面ZnO纳米棒样品,溶液温度约为97℃,时间为3小时。将合成的ZnO纳米棒烧制后,其电阻增加了数倍。利用扫描电子显微镜和x射线衍射对制备的纳米棒阵列的化学成分和形貌进行了表征。研究结果表明,ZnO纳米颗粒阵列对可见光的响应能力大大提高。本文的结果可用于其他金属氧化物的组合,也为进一步开发高性能的太阳能转换光电化学装置提供了许多有趣的机会。科学研究的结果是替代能源最重要的材料数据,可以被工业专家用于创建光电化学系统,通过与氧化锌形成水分解系统的活性光电阳极层来产生氢燃料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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