EFFECT OF H2O2 AND MnO2 AS OXIDATORS OF GOLD AND COPPER LEACH PROCESSES FROM PRINTED CIRCUIT BOARDS

Y. Pratesa, A. Wibisono, W. Putra, Y. Sadeli, A. Zakiyuddin, S. Harjanto
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引用次数: 1

Abstract

In general, electronic waste management in the form 2 of printed circuit boards (printed circuit boards/PCBs) is carried out by the process of removing components and taking precious metals that are easily recycled. However, in Indonesia, the recycling process for extracting precious metals has not been much processed, even though they contain precious metals such as copper and gold. This research was conducted to find a more economical and environmentally friendly treatment process by using an oxidizer of Hydrogen Peroxide (H 2 O 2 ) and Manganese Oxide (MnO 2 ) and reducing the level of HCl used. Observation of metal leaching results using Atomic Adsroption Spectroscopy (AAS) showed the value of recovery (recovery) of gold and copper reached 59.1% and 59.8% for 0.5M HCl + 2.5% H 2 O 2 . However, the recovery value of copper has reached its optimum point at the addition of 1.5% H 2 O 2 . The use of 3% & 5% MnO 2 results in recovery values of 12% and 24% for gold and copper. Observation of the cross section shows the dissolution of the copper metal from the PCB and accompanied by a change in the color of the solution from clear to green, the more concentrated the more the amount of dissolved copper metal shows the characteristic of CuCl solution. The results of the comparison of the two types of oxidizers show that H 2 O 2 is better than MnO 2 in producing higher Cu and Au metals more than 3 times.
H2O2和MnO2作为氧化剂对印刷电路板中金和铜浸出过程的影响
一般来说,印刷电路板(印刷电路板/ pcb)形式2的电子废物管理是通过去除组件和提取易于回收的贵金属的过程进行的。然而,在印度尼西亚,提取贵金属的回收过程并没有得到太多的处理,即使它们含有铜和金等贵金属。本研究通过使用过氧化氢(h2o2)和氧化锰(mno2)作为氧化剂,降低HCl的用量,寻找一种更经济、更环保的处理工艺。原子吸附光谱(AAS)观察金属浸出结果表明,在0.5M HCl + 2.5% h2o2条件下,金、铜的回收率分别达到59.1%和59.8%。而铜的回收率在添加1.5% h2o2时达到最佳值。使用3%和5% mno2可使金和铜的回收率分别达到12%和24%。观察横截面可以看到PCB中铜金属的溶解,并伴随着溶液颜色从透明变为绿色的变化,越浓的铜金属溶解量越多,显示出CuCl溶液的特征。两种氧化剂的对比结果表明,h2o2比mno2在生成高铜、高金金属方面的效果要好3倍以上。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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