Development, Atmospheric Testing and Field Operation of a Fuel Flexible Gas Turbine Combustion System for Crude Oil Volatile Organic Compounds

Thijs Bouten, Nick Gralike, L. Axelsson
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Abstract

Volatile Organic Compounds (VOCs) evaporate from crude oil due to their volatile characteristics. These VOCs are conventionally vented, thereby contributing significantly to the harmful emission in the crude oil loading, storage and transport on offshore platforms, ships, storage tanks, terminals and shuttle tankers. The VOCs can be captured by a VOC recovery system, thereby reducing the harmful emissions significantly. The heavier fractions (mainly C3+) out of VOCs can be stored as liquid VOC (LVOC). The non-condensable fraction is a surplus gas (SVOC) mainly consisting out of lighter hydrocarbons and inert gases. The composition of LVOC and SVOC significantly varies depending on the type of crude oil. The application of both LVOC is challenging due to the high volatility, high dew point and varying compositions, while the SVOC is challenging because of the high variation in inert gas concentration, which depends on the crude oil level in the cargo tank. This paper will present the development and testing of a new tubular combustion system that can operate on the LVOC and SVOC from a VOC recovery unit as well as on LNG in case the VOC recovery plant is not operational. The challenges of the high variety in fuels are mainly translated in a dedicated fuel nozzle for the low calorific fuel combustor. This novel nozzle allows for stable operation on a wide variety of fuels with limited supply pressure requirements. The combustor has been tested in OPRA’s state-of-the-art atmospheric combustor test rig. Hereby various fuels have been supplied. The results presented in this paper focus on the validation of flame stability, operational window, turn down and emissions operating on different mixtures of low calorific gas (SVOC) and high calorific gas (LVOC, propane and natural gas). After successful completion of the atmospheric testing, a full-scale engine test has been performed with the OP16 gas turbine in OPRA’s engine test cell. Multiple gensets are installed on shuttle tankers and have been successfully commissioned with the various fuels. Operational experience from these sea trials are discussed. It has been proven that the OPRA OP16 gas turbine can utilize 100% of the VOC emissions recovered from the shuttle tanker, whereby power is supplied to the vessel. This results in a significant reduction of the ship’s emissions.
原油挥发性有机化合物燃料柔性燃气轮机燃烧系统的研制、大气试验和现场运行
挥发性有机化合物(VOCs)由于其挥发特性而从原油中蒸发。这些挥发性有机化合物通常是通过通风方式排放的,因此在海上平台、船舶、储油罐、码头和穿梭油轮的原油装载、储存和运输过程中,会产生大量有害排放。挥发性有机化合物可以被挥发性有机化合物回收系统捕获,从而大大减少有害排放物。挥发性有机化合物中较重的组分(主要是C3+)可以作为液态挥发性有机化合物(LVOC)储存。不可冷凝部分是一种剩余气体(SVOC),主要由较轻的碳氢化合物和惰性气体组成。低挥发性有机化合物(LVOC)和高挥发性有机化合物(SVOC)的组成因原油类型的不同而有显著差异。由于高挥发性、高露点和不同的成分,LVOC的应用具有挑战性,而SVOC的应用具有挑战性,因为惰性气体浓度的变化很大,这取决于货油舱中的原油液位。本文将介绍一种新型管状燃烧系统的开发和测试,该系统可以使用挥发性有机化合物回收装置的低挥发性有机化合物和低挥发性有机化合物,也可以在挥发性有机化合物回收装置不运行的情况下使用液化天然气。燃料种类繁多的挑战主要体现在用于低热量燃料燃烧器的专用燃料喷嘴上。这种新颖的喷嘴可以在各种燃料上稳定运行,供应压力要求有限。该燃烧器已在OPRA最先进的大气燃烧器测试台上进行了测试。特此提供各种燃料。本文的研究结果侧重于验证不同低热量气体(SVOC)和高热量气体(LVOC、丙烷和天然气)混合物的火焰稳定性、操作窗口、关降和排放量。在成功完成大气测试后,OPRA在发动机测试单元中使用OP16燃气轮机进行了全尺寸发动机测试。多个发电机组安装在穿梭油轮上,并已成功地使用各种燃料。讨论了这些海试的操作经验。已经证明,OPRA OP16燃气轮机可以利用从穿梭油轮回收的100% VOC排放,从而为船舶提供动力。这大大减少了船舶的排放量。
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