Comparison of Spectrophotometric Methods for Determination of Iron in Acid Cleaning, and Passivating Stainless Steel Solution by UV-VIS, ICP/MS, and FAAS

Abstract

Generally, more sophisticated techniques such as, flame atomic absorption (AAS), inductively coupled plasma spectrometer (ICP-MS), and UV/Visible Spectrophotometer were used to determine trace iron metals in pickling (acid cleaning), and passivating stainless steel solutions. Simple and novel spectrophotometric methods are described for simultaneous determination of iron. While these techniques provide excellent sensitivity and selectivity. The results were found to be in satisfactory agreement (shows no significant difference) with those acquired by the flame atomic absorption spectrophotometer (FAAS), UV-Vis Spectrometer, and ICP/MS techniques. The results shows that the concentration of iron are very close each other (less than 5.0%) in the pickling and passivating solutions.