Characterization of Carbon Fibers Recovered by Pyrolysis of Cured Prepregs and Their Reuse in New Composites

A. Fernández, C. Lopes, C. González, F. López
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引用次数: 12

Abstract

The applications of composite materials are rapidly growing. In the aeronautical sector, composites account for up to 50% of the weight of a modern typical commercial aircraft. However, the amount of composites currently recycled is less than 5% of the total amount produced. With environmental concerns becoming an increasingly influential topic, recy clability of composite materials is a key issue. Furthermore, several related European laws have been passed to minimize the environmental impact of composite structures and to make rational use of landfills. In this chapter, the authors analyze recycling tech - niques for carbon fiber composites with thermoset polymer matrix. The objective is to reuse the fibers in new, lower cost composites with similar properties. Starting from a pyrolysis step, followed by oxidation, an evaluation of the different parameters of the recycling process has been performed. The characterization of the fibers includes tensile tests, scanning electron microscopy, and Raman spectroscopy. The recycled fibers pre sented a reduction of their initial tensile strength lower than 10%. Then, remanufactur- ing of laminates using the recycled fibers was achieved by resin film infusion, obtaining laminates with properties similar to the brand-new composites. These results have the potential to be exploited by the automotive, aeronautical, wind energy, construction, and other sectors. significantly, independently of the oxidation time. These results still have to be investigated but are judged not to impact the properties of the remanufacture composites. the of the unidirection-ally aligned of film infusion method in of resulting ply thickness, disposition of the fiber/resin ratio, and porosity control. It provides a potential solution to prepreg production scraps with enhanced quality assurance, resulting in the reduction of toxic emissions. resulted lami nates presented similar content and shear properties as compared to the brand new composites.
固化预浸料热解回收碳纤维的表征及其在新型复合材料中的再利用
复合材料的应用日益广泛。在航空领域,复合材料占现代典型商用飞机重量的50%。然而,目前回收的复合材料的数量还不到总产量的5%。随着环境问题日益成为一个有影响力的话题,复合材料的可靠性是一个关键问题。此外,已经通过了几项有关的欧洲法律,以尽量减少复合结构对环境的影响,并合理利用垃圾填埋场。本章对热固性聚合物基碳纤维复合材料的回收技术进行了分析。目标是将这些纤维重新用于具有类似性能的新型低成本复合材料中。从热解步骤开始,接着是氧化,对回收过程的不同参数进行了评估。纤维的表征包括拉伸测试、扫描电子显微镜和拉曼光谱。再生纤维的初始抗拉强度降低10%以下。然后,利用回收纤维通过注入树脂膜对层压板进行再制造,得到与全新复合材料性能相近的层压板。这些结果有潜力被汽车、航空、风能、建筑和其他部门利用。重要的是,与氧化时间无关。这些结果仍有待研究,但被认为不会影响再制造复合材料的性能。单向排列的膜注入方法在产生的厚度、纤维/树脂比的配置和孔隙率控制方面的作用。它为预浸料生产废料提供了一个潜在的解决方案,提高了质量保证,减少了有毒物质的排放。结果表明,复合材料的含量和剪切性能与新型复合材料相似。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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