Fully spin-coated memory TFT

S. Mondal, V. Venkataraman
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Abstract

The trends of recent technology are moving towards building system on panel (SOP), system on glass (SOG) or `see through' display technologies as well as towards large area flexible electronics with cost effective process[1]-[2]. Therefore the technologists are focused on developing fully spin-coated low cost sol-gel Thin Film Transistor (TFT) with solution processed Indium Gallium Zinc Oxide (IGZO) as a semiconductor[3]. It is necessary to develop transparent memory TFT by complete low cost sol-gel spin-coating technique which is suitable for large area electronics. There are several reports on transparent memory technology with IGZO as channel layer. However, most of them are fabricated with sophisticated ultra-high vacuum technique or high temperature deposition. In addition, some memory devices are only UV-erasable (not electrically) [4]. Since most of the spin-coated dielectrics are not as good as films deposited by other techniques i.e. sputtering, e-beam deposition, Atomic Layer Deposition (ALD) etc, preventing memory leakage is very difficult. Recently, we demonstrated fully spin-coated two terminal capacitive memory devices with Aluminium Oxide Phosphate (ALPO) as a dielectric and Cadmium Telluride nanoparticle (CdTe-NP) as a charge storage centre [5]. However, these structures can be useful only for SOP or SOG technology and not suitable for flexible electronics due to the high temperature processing steps. Here, we demonstrate a fully sol-gel spin-coated electrically programmable (P/E) memory three terminal TFT device (without silicon technology) with sol-gel IGZO as a deep level charge storage centre as well as channel layer. ALPO was used as tunnelling and blocking layer to prevent the memory leakage. The entire processing was carried out in the normal lab environment with the temperature processing step as low as 350°C.
全自旋涂覆TFT存储器
最近技术的趋势是朝着面板上系统(SOP),玻璃上系统(SOG)或“透视”显示技术以及具有成本效益过程的大面积柔性电子产品发展[1]-[2]。因此,技术人员专注于开发完全自旋涂覆的低成本溶胶凝胶薄膜晶体管(TFT),以溶液处理的铟镓氧化锌(IGZO)为半导体[3]。采用完全低成本的溶胶-凝胶自旋镀膜技术开发适用于大面积电子领域的透明存储器TFT是必要的。以IGZO作为通道层的透明存储技术已有一些报道。然而,它们大多是用复杂的超高真空技术或高温沉积技术制造的。此外,一些存储设备只能紫外线擦除(非电擦除)[4]。由于大多数自旋镀膜电介质的性能不如其他技术如溅射、电子束沉积、原子层沉积(ALD)等沉积的薄膜,因此防止存储器泄漏是非常困难的。最近,我们展示了以磷酸铝(ALPO)作为电介质和碲化镉纳米颗粒(CdTe-NP)作为电荷存储中心的完全自旋涂层的两个终端电容性存储器件[5]。然而,这些结构只能用于SOP或SOG技术,由于高温加工步骤,不适合柔性电子产品。在这里,我们展示了一个完全溶胶-凝胶自旋涂覆的电可编程(P/E)存储器三终端TFT器件(无硅技术),其溶胶-凝胶IGZO作为深层电荷存储中心和通道层。采用ALPO作为隧道和阻塞层,防止内存泄漏。整个加工过程在正常的实验室环境中进行,加工步骤温度低至350℃。
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