Analysis on High Temperature Gasification for Conversion of RDF into Bio-Methanol

A. Salladini, E. Agostini, A. Borgogna, L. Spadacini, M. Annesini, G. Iaquaniello
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引用次数: 5

Abstract

Municipal solid waste (MSW) is one of the residue materials considered as a potential source for biofuel production in the EU Renewable Energy Directive (RED), which estab-lishes that a minimum of 10% biofuels for transport shall be used in every Member State by 2020, thus promoting advanced biofuel from waste. A high-temperature gasification technology transforms MSW into a syngas rich in hydrogen and carbon monoxide and free of tar, char and harmful compounds like dioxins appearing as a promising root for methanol production. The overall process including MSW high-temperature gasification, syngas purification and conditioning up to methanol synthesis has been modeled with Aspen Plus analyzing the influence of waste composition and operating conditions on syngas composition and methanol yield. The evaluation of CAPEX and OPEX has been carried out to obtain a cost of production (COP) estimation. The greenhouse gas (GHG) emission has also been estimated and compared with the conventional waste incineration process and methanol production. The technology assessment shows interesting results technically and economically, when compared with waste to energy processes: over 50% of incoming carbon is fixed into methanol molecule, and due to the negative cost paid for RDF disposal, the bio-methanol COP provides a reasonable industrial margin.
RDF转化为生物甲醇的高温气化分析
城市固体废物(MSW)是欧盟可再生能源指令(RED)中被认为是生物燃料生产潜在来源的残留材料之一,该指令规定,到2020年,每个成员国至少要使用10%的运输生物燃料,从而促进从废物中提取先进生物燃料。高温气化技术将城市生活垃圾转化为富含氢气和一氧化碳的合成气,不含焦油、木炭和二恶英等有害化合物,有望成为甲醇生产的基础。利用Aspen Plus对城市生活垃圾高温气化、合成气净化和调理直至甲醇合成的整个过程进行了建模,分析了废物组成和操作条件对合成气组成和甲醇收率的影响。对CAPEX和OPEX进行了评估,以获得生产成本(COP)估算。温室气体(GHG)排放量也进行了估计,并与传统的垃圾焚烧工艺和甲醇生产进行了比较。与废物转化为能源的过程相比,技术评估在技术和经济上都显示出有趣的结果:超过50%的碳被固定到甲醇分子中,并且由于为RDF处理支付的负成本,生物甲醇COP提供了合理的工业边际。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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