Consequences of microphysical segregation of chemical elements in welded steels

V. A. Bigeev, A. B. Sychkov, M. V. Potapova, G. Y. Kamalova
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Abstract

Defects of metallurgy-originated steel (sub-cored bubbles, impurities, macro- and micro-segregations of chemical elements, nonmetallic inclusions) to a large extent determines the faultiness of metal rolled products. The processes of chemical elements segregation in steel macro- and micro volumes considerably influence its quality. Reasons of microphysical dendrite segregation originating in steels of welding purpose of Св-09Г2С and Св-08ГНМ type considered. Mechanism of dendrites formation studied as well as the segregation degree of chemical elements along the continuously casted billet cross section. To estimate the segregation degree a criteria was used – the segregation coefficient, determined as relation of chemical elements mass shares in different micro-areas (dendrites, inter-dendrite gaps) of continuously casted billet cross section to those elements content by a ladle analysis of a heat or one another in different micro-areas. A heredity of segregation transfer from CC billet to finished wire rod of Св-08Г2С and Св-08ГНМ steels studied. It was determined, that decrease of the number of bainite-martensite areas as a result of decrease of dendrite segregation of chemical elements takes place by minimization within grade chemical composition of both main alloying element and impurities ones. Besides an additional alloying of steel by boron takes place based on boron to nitrogen relation at the level of B/N = 0,8±0,15. It was shown that to decrease the inter-dendrite segregation it is necessary to elaborate and implement effective steel modifying by calcium and REMs regimes as well as electro-magnetic stirring during continuous casting.
焊接钢中化学元素微物理偏析的后果
冶金源钢的缺陷(亚芯气泡、杂质、化学元素的宏观和微观偏析、非金属夹杂物)在很大程度上决定了金属轧制产品的缺陷。钢中化学元素偏析的过程对钢的宏观和微观质量影响很大。研究了Св-09Г2С和Св-08ГНМ型焊接用钢中产生枝晶偏析的原因。研究了连铸方坯枝晶的形成机理及化学元素沿截面的偏析程度。为了估计偏析程度,使用了一个标准-偏析系数,该系数由连铸坯横截面不同微区域(枝晶,枝晶间间隙)的化学元素质量份额与这些元素含量的关系确定,通过钢包热分析或在不同微区域的相互分析。研究了Св-08Г2С和Св-08ГНМ钢连铸坯向成品线材偏析转移的遗传规律。结果表明,在主合金元素和杂质元素的化学成分等级内,使化学元素枝晶偏析减少,从而使贝氏体-马氏体区域数量减少。此外,在B/N = 0,8±0,15的水平上,硼对钢的附加合金化是基于硼氮关系的。结果表明,为了减少枝晶间偏析,有必要在连铸过程中精心设计并实施有效的钙、REMs和电磁搅拌改性钢。
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