Treatment of corrosion inhibitor in highly mineralized gas field water by advanced oxidation technology

Jinzhong Zhang, Xiangru Fan, L. B. Yun, Donghe Zhang, Yang Yijin
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Abstract

With more and more oil and gas fields being exploited at home and abroad, serious corrosion problems have been caused to gathering and transportation pipelines, which has become a major problem affecting the safe production and transportation of oil and gas. Corrosion inhibitor is one of the most commonly used protection measures in oil and gas wells and gathering and transportation systems, which has the advantages of low investment, quick effect, simple equipment, and easy operation, and basically does not change the properties of related metal components and media. This paper studies the addition of a corrosion inhibitor (CPI-W) whose main component is fatty acid imidazoline to 8 representative simulated gas field waters, and then determines the COD value change range and the law of gas field wastewater, and selects three representative ones. The effective water treatment oxidant degrades the CPI-W corrosion inhibitor (concentration 1000ppm) in 8 kinds of gas field water. The results show that with the increase of CPI-W dosage, COD values of 8 kinds of gsd field water all increase rapidly. Three advanced oxidation technologies, such as sodium hypochlorite method, Fenton reagent method and potassium persulfate-ferrous sulfate method,
先进氧化技术处理高矿化气田水中缓蚀剂
随着国内外油气田的开发越来越多,集输管道腐蚀问题严重,已成为影响油气安全生产和运输的重大问题。缓蚀剂是油气井和集输系统中最常用的保护措施之一,具有投资少、见效快、设备简单、操作方便等优点,基本不改变相关金属组分和介质的性质。本文研究了在8个具有代表性的模拟气田水中添加以脂肪酸咪唑啉为主要成分的缓蚀剂(CPI-W),确定了气田废水COD值的变化范围和变化规律,并选取了3个具有代表性的缓蚀剂。有效水处理氧化剂可降解8种气田水中CPI-W缓蚀剂(浓度1000ppm)。结果表明,随着CPI-W投加量的增加,8种gsd田水的COD值均迅速升高。次氯酸钠法、芬顿试剂法和过硫酸钾-硫酸亚铁法三种先进的氧化技术,
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