Fabrication of activated carbon electrode synthesized from sacred lotus leaf natural materials for supercapacitors

Tanachai Ponken, Kanoknan Yaowanit, Kanyaphat Weluwanarak, Apisit Keacharoen, Wichaid Ponhan
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Abstract

Supercapacitor has been the interesting issue in electric energy storage system. Supercapacitors carbon electrode was synthesized from a sacred lotus leaf. The none activated carbon sacred lotus leaf powder (CSLL) and the carbon sacred lotus leaf were mixed with potassium hydroxide (KOH) in the ratio of 1 : 1, 1 : 2, and 1 : 3 which were called CSLL, CSLL-1 : 1, CSLL-1 : 2 and CSLL-1 : 3, respectively. The structural, morphological properties and element component were analyzed with x-ray diffraction (XRD) technique, the field emission scanning electron microscope (FESEM) and energy dispersive x-ray spectroscopy (EDX), respectively. Electrical properties were measured by cyclic voltammetry (CV) and charge–discharge techniques. JCPDS 01-072-2091 data file confirmed the carbon-like (110) plan at 2 theta of 29.43° CSLL-1 : 1 and CSLL-1 : 2 showed high crystalline sizes. Morphology of CSLL-1 : 1 and CSLL-1 : 2 samples exhibited corrosion of surface clearly nevertheless carbon cluster adhered continuously on surface affect to higher the surface area. Carbon element of CSLL, CSLL-1 : 1 and CSLL-1 : 2 samples were obtained as high as of 74.50, 79.30 and 76 % by atomic, respectively which it was suitable characteristic of activated carbon electrode. The highest specific capacitance of CSLL-1 : 2 electrodes displayed approximately 40.85 F g-1 at the scan rate of 20 mVs-1. Moreover, the charge–discharge time of CSLL-1 : 1 and CSLL-1 : 2 electrodes showed the long discharge time more than the discharge time of CSLL-1 : 3 and CSLL electrodes. The performances of electrode demonstrated with charge-discharge of 1,500 and 1,000 cycles found that the CSLL-1 : 1 and CSLL-1 : 2 electrodes exhibited high stability. The suitable conditions ranges depicted between from the CSLL-1 : 1 to CSLL-1 : 2 ratios; furthermore, a sacred lotus leaf can fabricate the carbon electrode for supercapacitor.
圣荷叶天然材料合成超级电容器用活性炭电极的制备
超级电容器一直是电力储能系统研究的热点问题。以圣荷叶为原料合成了超级电容器碳电极。将无活性炭圣荷叶粉(CSLL)和炭圣荷叶粉与氢氧化钾(KOH)按1:1、1:1、1:3的比例混合,分别称为CSLL、CSLL- 1:1、CSLL- 1:1、CSLL- 1:1和CSLL- 1:3。分别用x射线衍射(XRD)、场发射扫描电镜(FESEM)和能量色散x射线能谱(EDX)分析了材料的结构、形态和元素成分。电学性能采用循环伏安法和充放电技术进行测定。JCPDS 01-072-2091数据文件证实,在29.43°2 θ位置的csll - 1:1和csll - 1:1处的类碳(110)平面显示出高晶粒尺寸。csll - 1:1和csll - 1:2样品的形貌表现出明显的表面腐蚀现象,但碳团簇在表面的持续粘附对表面积的影响较大。CSLL、CSLL- 1:1和CSLL- 1:1样品的碳元素原子含量分别高达74.50、79.30和76%,符合活性炭电极的特性。在扫描速率为20 mVs-1时,csll - 1:2电极的最高比电容约为40.85 F -1。CSLL- 1:1和CSLL- 1:2电极的充放电时间比CSLL- 1:3和CSLL电极的放电时间更长。在1500和1000次充放电循环下,csll - 1:1和csll - 1:2电极表现出较高的稳定性。合适的条件范围从csll - 1:1到csll - 1:1之间;此外,神圣的荷叶可以用来制作超级电容器的碳电极。
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