Sludge conditioning after pipe-rolling mill aggressive sewage waters neutralization

N. Tsarev, E. M. Тат’yannikova, V. Mozgovoy
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Abstract

. Many sewage treatment facilities of metallurgical plants are physically obsolescent. Frequent practice is joint neutralization of spent pickling solutions (SPS) and rinsing waters (RW) by lime mortar followed by discharge of such “neutralized” aggressive sewage water in collectors of wastes. Therefore, implementation of modern equipment and technologies for cleaning of aggressive sewage water is an extremely actual task. The purpose of the work – to select a scientifically based type of flocculants and their optimal dozes for sludge, formed at the SPS and RW neutralization, processing. Results of the studies of flocculants processing of existing sewage treatment facilities (neutralization stations) sludge of one of pipe-producing plant of Ural quoted. Really formed sludge of two types were studied: the sludge after neutralization of pickling solutions and the sludge of rinsing water. In the course of the work, the effectiveness of application of high-molecular flocculants of cation, anion and non-ion types was estimated for conditioning of the sludge. As the criteria of the flocculants effectiveness the minimal time of capillary water suction from the processed by flocculants sludge, determined by special timer of capillary suction and chromatographic paper Whatman 17 Chr. As a result of the studies carried out, it was determined that for conditioning of a sludge of SPS neutralization, the non-ion flocculants Praestol 2500 (the doze 5 kg/t) was most effective. For a sludge of RW neutralization the anion flocculants Praestol 2540 (the doze 2 kg/t) was found to be most effective. After proposed flocculants, processing the sludge can be directed for concentration and mechanical dewatering. The conditioning of the sludge by flocculants will enable to increase the productivity of dewatering equipment.
轧管机强力污水中和后的污泥调理
. 许多冶炼厂的污水处理设施设备陈旧。常用的做法是用石灰砂浆联合中和废酸洗溶液(SPS)和漂洗水(RW),然后将这种“中和”的腐蚀性污水排放到废物收集器中。因此,采用现代设备和技术来清洗腐蚀性污水是一项非常实际的任务。本研究的目的是为SPS和RW中和处理形成的污泥选择一种科学的絮凝剂及其最佳配比。介绍了乌拉尔某管制厂现有污水处理设施(中和站)污泥絮凝剂处理的研究结果。研究了两种真正形成的污泥:酸洗液中和后的污泥和漂洗水中和后的污泥。在工作过程中,评价了阳离子型、阴离子型和非离子型高分子絮凝剂对污泥的调理效果。用专用毛细管吸水定时器和色谱纸测定絮凝剂处理后污泥的毛细管吸水最短时间,作为絮凝剂效果的衡量标准。研究结果表明,对于SPS中和污泥的调理,非离子絮凝剂Praestol 2500(剂量为5 kg/t)最有效。对于废水中和污泥,阴离子絮凝剂Praestol 2540 (12 kg/t)最有效。采用所提出的絮凝剂后,污泥处理可直接进行浓缩和机械脱水。絮凝剂对污泥的调理可以提高脱水设备的生产效率。
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