Degradation of levofloxacin from antibiotic wastewater by pulse electrochemical oxidation with BDD electrode.

Abstract

Antibiotic-containing wastewater is a typical biochemical refractory organic wastewater and general treatment methods cannot effectively and quickly degrade the antibiotic molecules. In this study, a novel boron-doped diamond (BDD) pulse electrochemical oxidation (PEO) technology was proposed for the efficient removal of levofloxacin (LFXN) from wastewater. The effects of current density (j), initial pH (pH₀), frequency (f), electrolyte types and initial concentration (c₀(LFXN)) on the degradation of LFXN were systematically investigated. The degradation kinetics under four different processes have also been studied. The possible degradation mechanism of LFXN was proposed by Density functional theory calculation and analysis of degradation intermediates. The results showed that under the optimal parameters, the COD removal efficiency (η(COD)) was 94.4% and the energy consumption (EEC) was 81.43 kWh·m^-3 at t = 120 min. The degradation of LFXN at pH = 2.8/c(H₂O₂) followed pseudo-first-order kinetics. The apparent rate constant was 1.33 × 10^-2 min^-1, which was much higher than other processes. The degradation rate of LFXN was as follows: pH = 2.8/c(H₂O₂) > pH = 2.8 > pH = 7/c(H₂O₂) > pH = 7. Ten aromatic intermediates were formed during the degradation of LFXN, which were further degraded to F^-, NH₄⁺, NO₃^-, CO₂ and H₂O. This study provides a promising approach for efficiently treating LFXN antibiotic wastewater by pulsed electrochemical oxidation with a BDD electrode without adding H₂O₂.