在沥青/聚合物混合物中显示硬/软松弛

Didier Lesueur , Jean-François Gérard , Didier Martin , Jean-Pascal Planche
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引用次数: 2

摘要

在非均相聚合物改性沥青(PMB)中观察到微机械弛豫。Fröhlich和Sack从理论上研究了这种弛豫,当分散相颗粒发生微观弹性变形时,就会出现这种弛豫。因此,当材料在低应变动态机械变形下剪切时,两个增强域被突出显示:在低频下,富含聚合物的分散颗粒比基体更硬,表现为硬球体(不可变形的夹杂物)。在高频率下,它们是软的(可变形的),导致PMB的模量随后下降。硬/软弛豫导致最小的相位角与频率。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Mise en évidence d’une relaxation dur/mou dans un mélange bitume/polymère

A micromechanical relaxation is observed in a heterogeneous Polymer Modified Bitumen (PMB). This relaxation, theoritically studied by Fröhlich and Sack, arises when a microscopic elastic deformation develops in dispersed phase particles. Thus, two reinforcement domains are highlighted when the material is sheared under a low-strain dynamic mechanical deformation: at low frequency, the polymer-rich dispersed particles are harder than the matrix and behave as hard spheres (undeformable inclusions). At high frequencies, they are soft (deformable), causing a subsequent decrease in the modulus of the PMB. The hard/soft relaxation results in a minimum of phase angle versus frequency.

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