{"title":"二茂铁醇分子内相互作用焓","authors":"A.W. Baker, D.E. Bublitz","doi":"10.1016/0371-1951(66)80223-0","DOIUrl":null,"url":null,"abstract":"<div><p>The ν<sub>OH</sub> bands of a series of ferrocenyl alcohols and phenols have been studied as a function of temperature in carbon tetrachloride. From this, enthalpies have been calculated for the interaction of the hydroxyl group with both the ferrocenyl π-electrons and the <em>d</em>-orbitals of iron. The accessibility of the iron <em>d</em>-orbitals has been compared with those of the <em>d</em>-orbitals in the corresponding ruthenium and osmium compounds.</p></div>","PeriodicalId":101180,"journal":{"name":"Spectrochimica Acta","volume":"22 10","pages":"Pages 1787-1799"},"PeriodicalIF":0.0000,"publicationDate":"1966-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0371-1951(66)80223-0","citationCount":"34","resultStr":"{\"title\":\"Enthalpies of intramolecular interactions in ferrocenyl alcohols\",\"authors\":\"A.W. Baker, D.E. Bublitz\",\"doi\":\"10.1016/0371-1951(66)80223-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The ν<sub>OH</sub> bands of a series of ferrocenyl alcohols and phenols have been studied as a function of temperature in carbon tetrachloride. From this, enthalpies have been calculated for the interaction of the hydroxyl group with both the ferrocenyl π-electrons and the <em>d</em>-orbitals of iron. The accessibility of the iron <em>d</em>-orbitals has been compared with those of the <em>d</em>-orbitals in the corresponding ruthenium and osmium compounds.</p></div>\",\"PeriodicalId\":101180,\"journal\":{\"name\":\"Spectrochimica Acta\",\"volume\":\"22 10\",\"pages\":\"Pages 1787-1799\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1966-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0371-1951(66)80223-0\",\"citationCount\":\"34\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectrochimica Acta\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0371195166802230\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0371195166802230","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Enthalpies of intramolecular interactions in ferrocenyl alcohols
The νOH bands of a series of ferrocenyl alcohols and phenols have been studied as a function of temperature in carbon tetrachloride. From this, enthalpies have been calculated for the interaction of the hydroxyl group with both the ferrocenyl π-electrons and the d-orbitals of iron. The accessibility of the iron d-orbitals has been compared with those of the d-orbitals in the corresponding ruthenium and osmium compounds.
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