{"title":"氢键的研究——十六。五氟苯酚与氧化三苯基膦的络合","authors":"T. Gramstad, G. van Binst","doi":"10.1016/0371-1951(66)80213-8","DOIUrl":null,"url":null,"abstract":"<div><p>It has been found that pentafluorophenol (PFP) forms hydrogen-bonded complexes with triphenylphosphine oxide (TPPO) of the type 1:1, 2:1 and 1:2. The <em>K</em><sub>ass</sub>, Δ<em>F</em>, Δ<em>H</em> and Δ<em>S</em> values for the various complexes have been determined.</p><p>The infra-red spectra in the OH stretching vibration region for mixtures of various proton acceptors with PFP in carbon tetrachloride have been compared with the corresponding spectra using respectively phenol, pentabromophenol or pentachlorophenol as proton donor.</p></div>","PeriodicalId":101180,"journal":{"name":"Spectrochimica Acta","volume":"22 10","pages":"Pages 1681-1696"},"PeriodicalIF":0.0000,"publicationDate":"1966-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0371-1951(66)80213-8","citationCount":"20","resultStr":"{\"title\":\"Studies of hydrogen bonding—XVI the complexing of pentafluorophenol with triphenylphosphine oxide\",\"authors\":\"T. Gramstad, G. van Binst\",\"doi\":\"10.1016/0371-1951(66)80213-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>It has been found that pentafluorophenol (PFP) forms hydrogen-bonded complexes with triphenylphosphine oxide (TPPO) of the type 1:1, 2:1 and 1:2. The <em>K</em><sub>ass</sub>, Δ<em>F</em>, Δ<em>H</em> and Δ<em>S</em> values for the various complexes have been determined.</p><p>The infra-red spectra in the OH stretching vibration region for mixtures of various proton acceptors with PFP in carbon tetrachloride have been compared with the corresponding spectra using respectively phenol, pentabromophenol or pentachlorophenol as proton donor.</p></div>\",\"PeriodicalId\":101180,\"journal\":{\"name\":\"Spectrochimica Acta\",\"volume\":\"22 10\",\"pages\":\"Pages 1681-1696\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1966-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0371-1951(66)80213-8\",\"citationCount\":\"20\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectrochimica Acta\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0371195166802138\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0371195166802138","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Studies of hydrogen bonding—XVI the complexing of pentafluorophenol with triphenylphosphine oxide
It has been found that pentafluorophenol (PFP) forms hydrogen-bonded complexes with triphenylphosphine oxide (TPPO) of the type 1:1, 2:1 and 1:2. The Kass, ΔF, ΔH and ΔS values for the various complexes have been determined.
The infra-red spectra in the OH stretching vibration region for mixtures of various proton acceptors with PFP in carbon tetrachloride have been compared with the corresponding spectra using respectively phenol, pentabromophenol or pentachlorophenol as proton donor.
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