G.C. Kulasingam, W.R. McWhinnie, Rosemary R. Thomas
{"title":"某些含有2-吡啶基的化合物的红外光谱(650-222 cm−1)","authors":"G.C. Kulasingam, W.R. McWhinnie, Rosemary R. Thomas","doi":"10.1016/0371-1951(66)80040-1","DOIUrl":null,"url":null,"abstract":"<div><p>The infra-red spectra (650-222 cm<sup>−1</sup>) of nine 2-substituted pyridines, including those of four 2-pyridylamines, have been recorded. Solid compounds have been examined as mulls and as chloroform and/or carbon tetrachloride solutions and pronounced solid state effects were noted in one case. Empirical assignments of the major bands have been attempted and it is concluded that ν<sub>6<em>b</em></sub>-α(<em>CCC</em>), ν<sub>11</sub>-X-sens φ(<em>CC</em>) and ν<sub>16<em>a</em></sub>8φ(<em>CC</em>) may be assigned with some certainty even when the molecular complexity is considerable.</p></div>","PeriodicalId":101180,"journal":{"name":"Spectrochimica Acta","volume":"22 7","pages":"Pages 1365-1369"},"PeriodicalIF":0.0000,"publicationDate":"1966-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0371-1951(66)80040-1","citationCount":"10","resultStr":"{\"title\":\"The infra-red spectra (650-222 cm−1) of some compounds containing the 2-pyridyl group\",\"authors\":\"G.C. Kulasingam, W.R. McWhinnie, Rosemary R. Thomas\",\"doi\":\"10.1016/0371-1951(66)80040-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The infra-red spectra (650-222 cm<sup>−1</sup>) of nine 2-substituted pyridines, including those of four 2-pyridylamines, have been recorded. Solid compounds have been examined as mulls and as chloroform and/or carbon tetrachloride solutions and pronounced solid state effects were noted in one case. Empirical assignments of the major bands have been attempted and it is concluded that ν<sub>6<em>b</em></sub>-α(<em>CCC</em>), ν<sub>11</sub>-X-sens φ(<em>CC</em>) and ν<sub>16<em>a</em></sub>8φ(<em>CC</em>) may be assigned with some certainty even when the molecular complexity is considerable.</p></div>\",\"PeriodicalId\":101180,\"journal\":{\"name\":\"Spectrochimica Acta\",\"volume\":\"22 7\",\"pages\":\"Pages 1365-1369\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1966-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0371-1951(66)80040-1\",\"citationCount\":\"10\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectrochimica Acta\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0371195166800401\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0371195166800401","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The infra-red spectra (650-222 cm−1) of some compounds containing the 2-pyridyl group
The infra-red spectra (650-222 cm−1) of nine 2-substituted pyridines, including those of four 2-pyridylamines, have been recorded. Solid compounds have been examined as mulls and as chloroform and/or carbon tetrachloride solutions and pronounced solid state effects were noted in one case. Empirical assignments of the major bands have been attempted and it is concluded that ν6b-α(CCC), ν11-X-sens φ(CC) and ν16a8φ(CC) may be assigned with some certainty even when the molecular complexity is considerable.