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引用次数: 26
摘要
利用红外光谱和拉曼光谱对亚磷酸三甲酯的振动谱进行了划分。通过将亚磷酸三甲酯的红外和拉曼数据与已知的三氟化磷和磷酸三甲酯的红外和拉曼数据进行比较，辅助了分配。对实验数据的解释表明，亚磷酸三甲酯的对称性可能小于C3υ或C3。在亚磷酸盐和磷酸盐中提出了ν symp (- o -)3的初步相关性。
Infrared and Raman data were used to assign the vibrational spectrum of trimethyl phosphite. The assignment was aided by comparison of the infrared and Raman data for trimethyl phosphite with the known infrared and Raman data and assignments for phosphorous triflouride and trimethyl phosphate.
The interpretation of the experimental data suggest that the symmetry of trimethyl phosphite could be less than C3υ or C3.
A tentative correlation is suggested for νsym.P(-O-)3 in phosphites and phosphates.
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