Francesco Arena, Giampietro Cum, Raffaele Gallo, Adolfo Parmaliana
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Palladium-based catalysts supported on oligomeric aramides. A TPR investigation
The reduction pattern of PdCl2 supported on oligomeric aramides has been investigated by temperature programmed reduction (TPR) measurements in the range of temperature −80 to 305°C. The influence both of chemical composition of the oligomeric matrix and Pd loading has been ascertained. A peculiar metal—support interaction greatly affects the reducibility of Pd, allowing its stabilisation in the oxidised form (i.e., Pd2+).
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