采珠湾沉积物中铁形态的季节性变化Mössbauer光谱分析

A. Kuno, M. Matsuo, S. Chiba, Y. Yamagata
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引用次数: 1

摘要

日本中部三重县的阿古湾因其母珍珠文化而闻名于世,但最近珍珠产量大幅下降。湾的环境恶化被怀疑是造成数量下降的原因。利用57 Fe穆斯堡尔谱对海湾沉积物的铁形态进行周期性研究,发现其从表层到20cm深度的黄铁矿(FeS2)含量较高。表层沉积物中的黄铁矿仅在春季减少,而春季是在底水溶解氧达到最大值后的3个月。通过长期生物活动积累的黄铁矿等耗氧物质很可能是海湾环境长期恶化的原因,表现为沉积物的高化学需氧量(COD)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Seasonal Variation of Iron Speciation in a Pearl-Raising Bay Sediment by Mössbauer Spectroscopy
Ago Bay in Mie Prefecture, central Japan, is world-famous for the site of Mikimoto pearl culture, but recently the production of pearls has considerably declined. Environmental deterioration of the bay is suspected of having caused the decline. The periodic investigation into iron speciation of the bay sediment by 57 Fe Mossbauer spectroscopy revealed its high pyrite (FeS2) content from the surface to the 20-cm depth. The pyrite in the surface sediment decreased only in spring, three months after the dissolved oxygen in the bottom water was at maximum. Such oxygen-consuming material as pyrite accumulated through long-term biotic activity is a most-likely explanation for the prolonged environmental deterioration of the bay, which appears in the high chemical oxygen demand (COD) of the sediment.
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