中、重质原油在线电聚结装置的性能测试

Ed Grave, M. D. Olson, A. Menchaca, R. Westra, M. R. Akdim
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引用次数: 10

摘要

脱水在原油生产加工过程中起着至关重要的作用。对于许多石油加工设施来说,从重质原油中去除水是一个挑战,即使只考虑了上层应用(Moraes et al. 2013)。对于处理介质原油,以及一般情况下任何高度乳化的碳氢化合物液体,例如高压应用和提高采收率(EOR)过程中获得的液体,这也会带来很大的挑战。除了使用机械手段将水和油分离之外,其他常见的强化脱水方法包括加热、使用化学破乳剂和静电处理(Silset 2008)。其他可能的技术有pH调节、过滤和膜分离(Eow等,2001年)。热处理能有效地破坏油包水(WIO)乳状液的稳定性;然而,它也是能源密集型的,通常会导致更大的系统占用空间。在传统应用中,资本和运营支出可能相当可观(Pruneda et al. 2005),而在海底、北极、偏远或边缘油田应用中,使用热处理要么在经济上不吸引人,要么不切实际。此外,水在油中的溶解度随着温度的升高而增加。随着石油在运输过程中冷却,游离水会从管道中脱落,这可能会导致流动保障问题。除此之外,热处理还会使挥发性碳氢化合物从液相中闪出,从而导致加热后的原油体积明显缩小,api比重降低(Manning and Thompson 1995)。这意味着仅通过热处理就能从原油中除去的水量是有实际和经济限制的。由于这个原因,热处理和破乳剂的组合是迄今为止最常用的强化脱水方法,因为许多原油乳状液在使用合适类型和浓度的破乳剂处理时会变得不稳定(Arnold and Stewart 1998;游民2008;Kelland 2009)在高温下。虽然化学处理需要相对较低的资本投资和较少的能源,但它可以承担相当大的运营成本,并且确保化学品不间断地供应到生产现场可能具有挑战性。虽然向任何生产设施供应化学品都是昂贵的,而且对天气条件、市场可用性或政治因素的变化很敏感,但向海底、北极、偏远或边缘油田供应化学品是一个更大的后勤和经济挑战。静电处理可以有效地破坏WIO乳剂。它也是用于破坏WIO乳液稳定性的最节能的方法之一(Eow等人,2001年),被认为是深水开发中从稠油中分离产出水的一项有利技术(Euphemio等人,2007年)。当它与化学和/或热处理结合使用时,它可以通过降低总体能耗,减少化学破乳剂的使用,或两者兼而有之,从而提高生产设施的经济性。静电聚结器产生的电场会影响油中分散水滴的极化,从而影响WIO乳液的形貌Copyright©2015 Society of Petroleum Engineers
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Performance Testing of an Inline Electrocoalescer Device With Medium and Heavy Crudes
Introduction Dehydration plays a fundamental role in the production and processing of crude oil. The removal of water from heavy crude is a challenge for many oil-processing facilities, even when only topside applications are considered (Moraes et al. 2013). It can also pose a big challenge for processing medium crudes, and in general for any highly emulsified hydrocarbon liquids, such as those obtained from high-pressure applications and enhanced-oil-recovery (EOR) processes. Besides using mechanical means to separate water from oil, other common methods of enhanced dehydration include heating, use of chemical demulsifiers, and electrostatic treatment (Silset 2008). Other possible techniques are pH adjustment, filtration, and membrane separation (Eow et al. 2001). Heat treatment can effectively destabilize water-in-oil (WIO) emulsions; however, it is also energy intensive and typically results in a larger system footprint. Capital and operational expenditure can be considerable in conventional applications (Pruneda et al. 2005), and the use of heat treatment is either economically unattractive or impractical in subsea, Arctic, remote, or marginal field applications. Further, the solubility of water in oil increases with temperature. As the oil cools during transportation, free water drops out in the pipeline, which could cause flow-assurance issues. Besides this, heat treatment causes volatile hydrocarbons to flash out of the liquid phase, which can result in appreciable volume shrinkage and API-gravity reduction in the heated crude oil (Manning and Thompson 1995). This means that there is a practical and economical limit in the amount of water that can be removed from crude oil through the use of heat treatment alone. For this reason, a combination of heat treatment and demulsifiers is by far the most-common method of enhanced dehydration because many crude-oil emulsions become unstable when treated with the right type and concentration of demulsifier (Arnold and Stewart 1998; Caird 2008; Kelland 2009) at high temperature. While chemical treatment requires a relatively lower capital investment and less energy than heat treatment, it can bear a considerable operating cost, and ensuring an uninterrupted supply of chemicals to the production site can be challenging. While the supply of chemicals to any production facility can be expensive and sensitive to changes in weather conditions, market availability, or political factors, the supply of chemicals to subsea, Arctic, remote, or marginal field applications is a far greater logistical and economical challenge. Electrostatic treatment can be effective at breaking WIO emulsions. It is also one of the most energy-efficient methods used for destabilization of WIO emulsions (Eow et al. 2001), and is considered an enabling technology for the subsea separation of produced water from heavy oil in deepwater developments (Euphemio et al. 2007). When it is used in combination with chemical and/or heat treatment, it can improve the economics of the production facility by reducing the overall energy consumption, by reducing the use of chemical demulsifier, or both. The electrical field produced by an electrostatic coalescer affects the morphology of WIO emulsions because of the polarization of dispersed water droplets in the oil Copyright © 2015 Society of Petroleum Engineers
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