{"title":"SF5取代氟碳聚合物的合成","authors":"H. Kawa, S. Partovi, B. J. Ziegler, R. Lagow","doi":"10.1002/POL.1990.140281001","DOIUrl":null,"url":null,"abstract":"Synthesis of both hydrocarbon and perfluorocarbon vinyl polymers containing the SF5 group have been accomplished by the reaction of elemental fluorine with poly (S-vinyl-O-t-butylthiocar bonate(. The resulting linear polymers have pendant SF5 groups with similar structures to polytetrafluoroethylene and polyethylene.","PeriodicalId":16874,"journal":{"name":"Journal of Polymer Science: Polymer Letters Edition","volume":"97 4","pages":"297-300"},"PeriodicalIF":0.0000,"publicationDate":"1990-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"A synthesis for SF5 substituted fluorocarbon polymers\",\"authors\":\"H. Kawa, S. Partovi, B. J. Ziegler, R. Lagow\",\"doi\":\"10.1002/POL.1990.140281001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Synthesis of both hydrocarbon and perfluorocarbon vinyl polymers containing the SF5 group have been accomplished by the reaction of elemental fluorine with poly (S-vinyl-O-t-butylthiocar bonate(. The resulting linear polymers have pendant SF5 groups with similar structures to polytetrafluoroethylene and polyethylene.\",\"PeriodicalId\":16874,\"journal\":{\"name\":\"Journal of Polymer Science: Polymer Letters Edition\",\"volume\":\"97 4\",\"pages\":\"297-300\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1990-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Polymer Science: Polymer Letters Edition\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/POL.1990.140281001\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Science: Polymer Letters Edition","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/POL.1990.140281001","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
摘要
通过单质氟与聚s -乙烯基- o -t-丁基硫酸盐反应，合成了含SF5基团的碳氢化合物和全氟碳乙烯基聚合物。所得到的线性聚合物具有与聚四氟乙烯和聚乙烯结构相似的悬垂SF5基团。
A synthesis for SF5 substituted fluorocarbon polymers
Synthesis of both hydrocarbon and perfluorocarbon vinyl polymers containing the SF5 group have been accomplished by the reaction of elemental fluorine with poly (S-vinyl-O-t-butylthiocar bonate(. The resulting linear polymers have pendant SF5 groups with similar structures to polytetrafluoroethylene and polyethylene.
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