微弧氧化涂层对挤压Mg-2Zn-0.5Zr-1.5Dy(质量%)合金耐腐蚀性能和力学性能的影响

Huan Li, J. Wen, Jie Jin, Ya Liu, Jun-guang He
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引用次数: 4

摘要

为了改善可生物降解镁合金在腐蚀性氯离子介质中较差的力学性能和耐腐蚀性,在挤压成型的Mg-2Zn-0.5Zr-1.5Dy(质量%)合金表面制备了氧化时间为3 ~ 15 min的微弧氧化涂层。分别通过电化学实验、析氢实验和拉伸试验进行了评估。结果表明:微弧氧化膜具有多孔性,主要由MgO相组成;当氧化时间从3 min增加到15 min时,涂层的厚度和孔径增大,而涂层的孔隙率减小。氧化时间为15 min的涂层可有效防止合金表面形成点孔,显著降低合金在模拟体液中浸泡0 ~ 28天后的极限抗拉强度、屈服强度和伸长率的衰减率,使合金具有更高、更稳定的耐腐蚀性。这增加了挤压Mg-2Zn-0.5Zr-1.5Dy合金作为生物降解材料的应用可能性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Roles of the micro‐arc oxidation coating on the corrosion resistance and mechanical properties of extruded Mg–2Zn–0.5Zr–1.5Dy (mass%) alloy
Aiming to enhance the biodegradable magnesium alloys' poor mechanical properties and corrosion resistance in aggressive chloride mediums, micro‐arc oxidation coatings with oxidation times range from 3 to 15 min were prepared on the surface of extruded Mg–2Zn–0.5Zr–1.5Dy (mass%) alloy. Assessments were carried out using electrochemical experiments, hydrogen evolution experiments, and tensile tests, respectively. The results show that the micro‐arc oxidation coating is porous and mainly consists of the MgO phase. When the oxidation time increases from 3 to 15 min, the thickness and the pore size of the coating increase, while the coating's porosity decreases. The coating with the oxidation time of 15 min can effectively prevent the formation of pitting holes on the surface of the alloy, which remarkably reduces the decay rate of ultimate tensile strength, yield strength, and elongation of the alloy after immersion in simulated body fluid for 0–28 days, and keep the alloy with higher and more stable corrosion resistance. This increases the application possibility of extruded Mg–2Zn–0.5Zr–1.5Dy alloy as a biodegradable material.
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