硫脲在氧化还原聚合中的作用

Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics Pub Date : 1984-01-01 DOI:10.1080/07366578408079451

G. S. Misra, U. Bajpai, J. Trekoval

{"title":"硫脲在氧化还原聚合中的作用","authors":"G. S. Misra, U. Bajpai, J. Trekoval","doi":"10.1080/07366578408079451","DOIUrl":null,"url":null,"abstract":"Abstract The use of organic and inorganic compounds belonging to the class of peroxides in the initiation of addition polymerization is well known. It has been found that the addition of small amounts of additives brings about the initiation of the polymerization of vinyl monomers with ease. Such polymerizations have been termed reduction-oxidation or redox. An example of such a reaction is the formation of hydroxy free radicals in the well-known reaction","PeriodicalId":16139,"journal":{"name":"Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics","volume":"10 3","pages":"335-353"},"PeriodicalIF":0.0000,"publicationDate":"1984-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"10","resultStr":"{\"title\":\"Role of Thiourea in Redox Polymerization\",\"authors\":\"G. S. Misra, U. Bajpai, J. Trekoval\",\"doi\":\"10.1080/07366578408079451\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract The use of organic and inorganic compounds belonging to the class of peroxides in the initiation of addition polymerization is well known. It has been found that the addition of small amounts of additives brings about the initiation of the polymerization of vinyl monomers with ease. Such polymerizations have been termed reduction-oxidation or redox. An example of such a reaction is the formation of hydroxy free radicals in the well-known reaction\",\"PeriodicalId\":16139,\"journal\":{\"name\":\"Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics\",\"volume\":\"10 3\",\"pages\":\"335-353\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1984-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"10\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/07366578408079451\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/07366578408079451","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 10

摘要

摘要过氧化物类的有机和无机化合物在加成聚合引发中的应用是众所周知的。研究发现，少量助剂的加入使乙烯基单体的聚合反应容易发生。这种聚合被称为还原-氧化或氧化还原。这种反应的一个例子是众所周知的反应中羟基自由基的形成

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Role of Thiourea in Redox Polymerization

Abstract The use of organic and inorganic compounds belonging to the class of peroxides in the initiation of addition polymerization is well known. It has been found that the addition of small amounts of additives brings about the initiation of the polymerization of vinyl monomers with ease. Such polymerizations have been termed reduction-oxidation or redox. An example of such a reaction is the formation of hydroxy free radicals in the well-known reaction

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics

自引率

0.00%

发文量