А. В. Дмитриенко, Евгений Валентинович Протопопов, В. И. Дмитриенко, Н. Ф. Якушевич, В. Ф. Горюшкин
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引用次数: 0
摘要
降低昂贵而稀缺的铁合金用量是提高铁冶金生产效率的方向之一。氧化物材料直接合金化钢的技术为这一方向提供了巨大的机会。对锰氧化物材料(锰矿石)直接合金化钢的过程进行了热力学研究,并对该工艺进行了工业试验。考虑了两种直接合金化技术的选择:在现代100吨电弧炉的氧化条件下熔化钢和在钢包炉(LF)的还原条件下加工钢。利用TERRA软件包对氧化工艺选项进行热力学建模,结果表明,注入锰矿石有可能提高金属中锰的含量。这个过程的关键因素是当前钢中的含碳量。在中高碳钢中,锰的含量可提高到0.6%以上。低碳钢的残锰量是由氧氧化结束时的含碳量来确定的。提供图形依赖。MnO + Si = Mn + sio2是还原条件下直接合金化过程的主要反应。热力学分析给出了非常粗略的数据。因此,本文采用了半经验分析的方法,以LF炼钢后期炉渣中FeO和MnO含量的工业实测结果为基础。由于该方法近似于LF长时间炼钢过程中金属渣体系的平衡,因此认为该方法是合理的。利用这一比例,在渣初碱度保持和渣中FeO含量保持在1%左右的条件下,推导出了钢包锰矿直接合金化钢过程的平衡方程。该方程可应用于具体生产条件,计算锰矿石直接合金化工艺的基本工艺参数。理论计算与实际数据具有较好的收敛性。
ИЗУЧЕНИЕ ПРОЦЕССА ПРЯМОГО ЛЕГИРОВАНИЯ СТАЛИ МАРГАНЦЕМ В УСЛОВИЯХ СОВРЕМЕННОГО ЭЛЕКТРОСТАЛЕПЛАВИЛЬНОГО ПРОИЗВОДСТВА
One of the directions of increasing production efficiency in ferrous metallurgy is reduction of expensive and scarce ferroalloy consumption. Great opportunities in that direction are provided by technology of direct steel alloying by oxide materials. Thermodynamic study of the process of direct steel alloying by manganese oxide materials (manganese ore) and industrial testing of that technology has been done in that work. Two options of direct alloying technology have been considered: during steel melting in modern 100-ton EAF in oxidative conditions and during processing of steel on ladle furnace (LF) in reductive conditions. Thermodynamic modeling of oxidative technology option by TERRA software package has shown that there is opportunity to increase content of manganese in metal by manganese ore injection. Key factor in that process is current carbon content in steel. Content of manganese can be raised up to 0.6 % and more in medium and high-carbon steel. Residual manganese in low-carbon steel is defined by value of carbon content in the end of oxygen lancing. Graphic dependence is provided. MnO + Si = Mn + SiO 2 is main reaction of the process of direct alloying under reductive conditions. Thermodynamic analysis gives very rough data. That is why semi-empirical analysis was performed, which was based on received industrial results of FeO and MnO proportion contained in slag in the end of steel processing at LF. That way of process estimation is considered reasonable, because of approximation to balance of metal-slag system during long processing of steel at LF. Using this proportion, and conditions of slag initial basicity retaining and maintaining of FeO content in slag at level around 1 %, balance equation describing process of direct steel alloying by manganese ore at ladle was derived. This equation helps to calculate basic technological parameters of the process of direct alloying by manganese ore as applied to specific conditions of production. Good convergence of theoretical calculation and practical data has been received.