根据卫星测量的大气中甲醛含量的时空变化

Q4 Chemistry
Yu. G. Kokosh, S. Kakareka
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引用次数: 0

摘要

甲醛(HCHO)是大气化学中的关键成分,是臭氧(O3)的前体,是大气光化学活性的重要指标。它也是一种人类和动物致癌物。为了评估甲醛含量的时空变化,本文分析了位于Aura卫星上的OMI光谱仪2003-2016年的长期测量数据。分析结果表明,2003-2016年白俄罗斯大部分地区对流层甲醛含量空间分布不均匀,从西南向东北方向呈下降趋势。大城市和工业中心形成了对流层污染增加的区域。在研究期间,白俄罗斯境内的电池中甲醛含量最高为30.8×1015 mol/cm2,平均为6.5×1015 mol/cm2。在大多数(84.1%)得到的值中,甲醛浓度固定在2.0-10.0×1015分子的范围内。/cm2,只有0.6%超过15.0×1015分子/cm2。将得到的数据与地面大气监测系统的数据进行了比较。白俄罗斯境内对流层以及大气表层的甲醛含量具有明显的季节性动态,在温暖季节达到最大值,7月和8月浓度最高。对表层和对流层柱中甲醛含量的年内动态分析表明,白俄罗斯整体和个别城市都存在一般趋势
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Spatiotemporal variability of formaldehyde content in atmospheric air according to satellite measurements
Formaldehyde (HCHO) is a key ingredient in atmospheric chemistry, a precursor to ozone (O3) and an important indicator of atmospheric photochemical activity. It is also known to be a human and animal carcinogen. To assess the spatial and temporal variability of the formaldehyde content, the article analyzes long-term data (2003–2016) of measurements of the OMI spectrometer located on the Aura satellite. The results of the analysis showed that the tropospheric content of formaldehyde over most of the territory of Belarus for 2003–2016 had an uneven spatial distribution: there is a decrease in concentrations in the direction from the southwest to the northeast. Large cities and industrial centers form zones of increased troposphere pollution. The content of formaldehyde in the cells over the territory of Belarus during the study period was in the range of up to 30.8×1015 mol/cm2 and averaged 6.5×1015 molec./cm2. In most of the obtained values (84.1 %), the formaldehyde concentrations were fixed within the range of 2.0–10.0×1015 molec./cm2, and only 0.6 % exceeded 15.0×1015 molec./cm2. The obtained data are compared with the data of the ground-based atmospheric air monitoring system. The content of formaldehyde in the troposphere over the territory of Belarus, as well as in the surface layer of the atmosphere, has a pronounced seasonal dynamics with a maximum in the warm season with the highest concentrations in July and August. An analysis of the intra-annual dynamics of formaldehyde content in the surface layer and in the troposphere column indicates the presence of general trends, both for Belarus as a whole and for individual cities.1
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