几种新型偶氮酯配体二氧铀配合物的合成与研究

A. Kishor, S. A.K, C. A.S.
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引用次数: 0

摘要

用偶氮酯配体合成了一些新的铀酰(VI)金属离子与不同阴离子(Cl-、I-、NO-3和OAc)的配合物。配合物的表征采用传统的方法,即熔点测量、电导率测量。这些也被现代光谱方法表征,即红外,包括远红外,紫外-可见。光谱。热研究,特别是差热分析的代表性研究也已完成和报道。对部分配合物进行了抗菌活性筛选。本文提出了配合物的配位数为8、10和12,并报道了配合物的初步结构。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and Studies of Some New Dioxouranium (VI) Complexes with Azoester Ligands
Some new complexes of uranyl (VI) metal ion with different anions (viz. Cl-,I-,NO-3 and OAc ) have been synthesized using azoester ligand. Complexes were characterized by traditional methods viz. melting point measurements, conductivity measurements. These were also characterized by modern spectral methods viz. IR including far IR, UV –vis. spectra. Thermal studies specially DTA studies of representative have also been done and reported. Some of the complexes were also screened against selected microbes to check their antimicrobial activities. Coordination number of these complexes are proposed to be 8, 10 and 12 and tentative structures of the complexes are also reported in the present paper.
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