{"title":"几种新型偶氮酯配体二氧铀配合物的合成与研究","authors":"A. Kishor, S. A.K, C. A.S.","doi":"10.9790/5736-1004011221","DOIUrl":null,"url":null,"abstract":"Some new complexes of uranyl (VI) metal ion with different anions (viz. Cl-,I-,NO-3 and OAc ) have been synthesized using azoester ligand. Complexes were characterized by traditional methods viz. melting point measurements, conductivity measurements. These were also characterized by modern spectral methods viz. IR including far IR, UV –vis. spectra. Thermal studies specially DTA studies of representative have also been done and reported. Some of the complexes were also screened against selected microbes to check their antimicrobial activities. Coordination number of these complexes are proposed to be 8, 10 and 12 and tentative structures of the complexes are also reported in the present paper.","PeriodicalId":14488,"journal":{"name":"IOSR Journal of Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2017-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Studies of Some New Dioxouranium (VI) Complexes with Azoester Ligands\",\"authors\":\"A. Kishor, S. A.K, C. A.S.\",\"doi\":\"10.9790/5736-1004011221\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Some new complexes of uranyl (VI) metal ion with different anions (viz. Cl-,I-,NO-3 and OAc ) have been synthesized using azoester ligand. Complexes were characterized by traditional methods viz. melting point measurements, conductivity measurements. These were also characterized by modern spectral methods viz. IR including far IR, UV –vis. spectra. Thermal studies specially DTA studies of representative have also been done and reported. Some of the complexes were also screened against selected microbes to check their antimicrobial activities. Coordination number of these complexes are proposed to be 8, 10 and 12 and tentative structures of the complexes are also reported in the present paper.\",\"PeriodicalId\":14488,\"journal\":{\"name\":\"IOSR Journal of Applied Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2017-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IOSR Journal of Applied Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.9790/5736-1004011221\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IOSR Journal of Applied Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.9790/5736-1004011221","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and Studies of Some New Dioxouranium (VI) Complexes with Azoester Ligands
Some new complexes of uranyl (VI) metal ion with different anions (viz. Cl-,I-,NO-3 and OAc ) have been synthesized using azoester ligand. Complexes were characterized by traditional methods viz. melting point measurements, conductivity measurements. These were also characterized by modern spectral methods viz. IR including far IR, UV –vis. spectra. Thermal studies specially DTA studies of representative have also been done and reported. Some of the complexes were also screened against selected microbes to check their antimicrobial activities. Coordination number of these complexes are proposed to be 8, 10 and 12 and tentative structures of the complexes are also reported in the present paper.