{"title":"盐酸匹洛卡品选择性电极的制备","authors":"A. M. Abass","doi":"10.22401/JNUS.20.4.03","DOIUrl":null,"url":null,"abstract":"New eight selective electrodes of pilocarpine hydrochloride deepened on complexes of (PCH) -molybdophosphoric acid and (PCH) – phosphotungstate were prepared with varied plasticizers. Electrode with complex (DBPH-MP) was used as an active material, gave linear range from 5.0×10-2 to 6.0×10-5 M, and slope was 62.01 mV/decade, with detection limit was 2.0×10-5M, lifetime was near to 60 days. Electrode,s membrane made with active material (DBP-MP), showed concentration range was 2.1×10-3-6.3×10-5M, the slope was near to 52.34 mV/decade. Detection limit was 1.0×10-5M, 55 days was the life time of this electrode. The parameters of electrode deepened on (DBPH-PT), concentration range was from 5.0×10-2 to 6.5×10-5 M with slope 50.41 mV/decade, 2.2×10-5 M was the detection limit.Life time was determined around to 52 days.","PeriodicalId":14922,"journal":{"name":"Journal of Al-Nahrain University-Science","volume":"54 1","pages":"13-19"},"PeriodicalIF":0.0000,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Preparation Pilocarpine Hydrochloride Selective Electrodes\",\"authors\":\"A. M. Abass\",\"doi\":\"10.22401/JNUS.20.4.03\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"New eight selective electrodes of pilocarpine hydrochloride deepened on complexes of (PCH) -molybdophosphoric acid and (PCH) – phosphotungstate were prepared with varied plasticizers. Electrode with complex (DBPH-MP) was used as an active material, gave linear range from 5.0×10-2 to 6.0×10-5 M, and slope was 62.01 mV/decade, with detection limit was 2.0×10-5M, lifetime was near to 60 days. Electrode,s membrane made with active material (DBP-MP), showed concentration range was 2.1×10-3-6.3×10-5M, the slope was near to 52.34 mV/decade. Detection limit was 1.0×10-5M, 55 days was the life time of this electrode. The parameters of electrode deepened on (DBPH-PT), concentration range was from 5.0×10-2 to 6.5×10-5 M with slope 50.41 mV/decade, 2.2×10-5 M was the detection limit.Life time was determined around to 52 days.\",\"PeriodicalId\":14922,\"journal\":{\"name\":\"Journal of Al-Nahrain University-Science\",\"volume\":\"54 1\",\"pages\":\"13-19\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2017-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Al-Nahrain University-Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.22401/JNUS.20.4.03\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Al-Nahrain University-Science","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.22401/JNUS.20.4.03","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
New eight selective electrodes of pilocarpine hydrochloride deepened on complexes of (PCH) -molybdophosphoric acid and (PCH) – phosphotungstate were prepared with varied plasticizers. Electrode with complex (DBPH-MP) was used as an active material, gave linear range from 5.0×10-2 to 6.0×10-5 M, and slope was 62.01 mV/decade, with detection limit was 2.0×10-5M, lifetime was near to 60 days. Electrode,s membrane made with active material (DBP-MP), showed concentration range was 2.1×10-3-6.3×10-5M, the slope was near to 52.34 mV/decade. Detection limit was 1.0×10-5M, 55 days was the life time of this electrode. The parameters of electrode deepened on (DBPH-PT), concentration range was from 5.0×10-2 to 6.5×10-5 M with slope 50.41 mV/decade, 2.2×10-5 M was the detection limit.Life time was determined around to 52 days.