{"title":"配位化合物的结构和机理研究。第二部分。反氯硝基和反溴四胺钴(III)阳离子的制备、水化和碱水解","authors":"C. Poon, H. Tong","doi":"10.1039/J19710002151","DOIUrl":null,"url":null,"abstract":"The preparation and characterization of trans-[Co(NH3)4NO2Cl]+ and trans-[Co(NH3)4NO2Br]+ cations are described. The assignment of geometric configuration is based on 1H n.m.r. spectroscopy. The kinetics of the aquation and base hydrolysis of these two complex cations have been studied over a range of temperature. The first-order aquation rate constants are greater than those of the corresponding bis(ethylenediamine) and 1,4,8,11-tetra-azacyclotetradecane complexes, whereas the second-order base hydrolysis rate constants are less. These results are consistent with the kinetic nephelauxetic effect of these amine ligands on the central cobalt(III) ion. Unimolecular reaction mechanisms are assigned to these reactions.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Structural and mechanistic studies of co-ordination compounds. Part II. Preparation, aquation, and base hydrolysis of trans-chloronitro- and trans-bromonitro-tetra-amminecobalt(III) cations\",\"authors\":\"C. Poon, H. Tong\",\"doi\":\"10.1039/J19710002151\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The preparation and characterization of trans-[Co(NH3)4NO2Cl]+ and trans-[Co(NH3)4NO2Br]+ cations are described. The assignment of geometric configuration is based on 1H n.m.r. spectroscopy. The kinetics of the aquation and base hydrolysis of these two complex cations have been studied over a range of temperature. The first-order aquation rate constants are greater than those of the corresponding bis(ethylenediamine) and 1,4,8,11-tetra-azacyclotetradecane complexes, whereas the second-order base hydrolysis rate constants are less. These results are consistent with the kinetic nephelauxetic effect of these amine ligands on the central cobalt(III) ion. Unimolecular reaction mechanisms are assigned to these reactions.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710002151\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710002151","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Structural and mechanistic studies of co-ordination compounds. Part II. Preparation, aquation, and base hydrolysis of trans-chloronitro- and trans-bromonitro-tetra-amminecobalt(III) cations
The preparation and characterization of trans-[Co(NH3)4NO2Cl]+ and trans-[Co(NH3)4NO2Br]+ cations are described. The assignment of geometric configuration is based on 1H n.m.r. spectroscopy. The kinetics of the aquation and base hydrolysis of these two complex cations have been studied over a range of temperature. The first-order aquation rate constants are greater than those of the corresponding bis(ethylenediamine) and 1,4,8,11-tetra-azacyclotetradecane complexes, whereas the second-order base hydrolysis rate constants are less. These results are consistent with the kinetic nephelauxetic effect of these amine ligands on the central cobalt(III) ion. Unimolecular reaction mechanisms are assigned to these reactions.
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