掺镍聚氨酯纳米复合材料的电性能研究

P. GangaRajuAchary, B. Munisha, S. Singhdeo, P. Ks
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引用次数: 3

摘要

用异戊二烯二异氰酸酯和聚乙二醇按1.2:1的比例配制成纯聚氨酯(PU)聚合物。将纳米镍添加到纯聚氨酯基体中,合成PU/Ni(25%)纳米复合材料。用红外光谱证实了纯聚氨酯和镍-聚氨酯纳米复合材料的形成。温度的变化对纳米复合材料的某些电性能(即切线损耗、电模量、交流电导率、奈奎斯特图等)产生了一些有趣的结果,对器件应用有用。由于在聚合物中加入纳米镍(作为填料),纯聚氨酯的电性能发生了巨大的变化。交流电导率的不断提高和高切线损耗使镍聚氨酯纳米复合材料成为一种智能材料,在储能、生物材料和形状记忆等方面具有重要的应用价值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study of Electrical Properties of Nickel Doped Polyurethane Nanocomposites
Isophorene diisocyanate and polyethylene glycol are taken in 1.2:1 ratio to prepared pure polyurethane (PU) polymer. The nickel nanoparticles are added into pure polyurethane matrix to synthesize PU/Ni (25%) nanocomposites. The formation of pure polyurethane and nickel-polyurethane nano-composites were confirmed FTIR spectra. The variation of temperature on some electrical properties (i.e. tangent loss, electrical modulus, ac conductivity, Nyquist plots etc.) of the nanocomposites has produced some interesting results useful for device applications. The electrical properties of pure polyurethane have drastically changed due to addition of nickel nanoparticles (as filler) in the polymer. The increasing tendency of ac conductivity and high tangent loss make nickelpolyurethane nano-composites as smart materials and very useful for energy storage, biomaterials and shape memory.
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