注气开采稠油的基础物理:油以油基乳化液形式存在时的实验参数分析

Mohammed Mohammedalmojtaba, Lixing Lin, Georgeta M. Istratescu, T. Babadagli, A. Zadeh, M. Anderson, Chris Patterson
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引用次数: 4

摘要

油藏中的稠油在水驱一次采油后,或者在注水、注汽等二次采油方法中,以稠油(w/ho)乳状液中的水形式存在。在许多情况下,决定采用第二或第三种方法,如注入CO2或CH4,取决于对储层条件下w/ho乳液中这些气体的行为的了解。这种认识可以通过为储层模拟和历史匹配研究提供充分的流体模型来减少储层建模中的不确定性。本文主要研究了(w/ho)乳剂中CO2和CH4的界面性质、相对体积变化和PVT行为。我们首先使用150℃的蒸汽生成(w/ho)乳液。接下来,使用不同的标准来测试我们的乳液的稳定性,如相分离、产出的乳液与起始油的粘度、连续介质中水滴的大小和数量。实验使用了从阿尔伯塔省东部两个代表性油田收集的两种重油,A型油(27,000 cP)和B型油(4,351 cP)。进行了敏感性分析,以确定不同操作变量(如乳液中含水量、水pH和流量)的影响;此外,还研究了沥青质和树脂对乳液稳定性的影响。发现乳状液中含水量的影响是至关重要的,因此随后的IFT和相对体积测量以及PVT分析使用了不同含水量的乳状液,体积百分比范围为10- 70%。结果与无水死油情况进行了比较。测试了两种通常用于提高阿尔伯塔采收率的气体:CO2和CH4。IFT和体积测量表明存在临界含水量,这极大地改变了系统的行为;通常,含水量低于该临界值的乳状液的IFT低于原始油,并且IFT随着含水量的增加而稳步下降。当含水率超过临界值时,这一趋势发生逆转,IFT在稳定之前开始增加。当含水量达到大于50%的体积%时,该过程发生;然而,它仍然低于原始油。在体积比方面,乳化液与CO2体系的压力和体积比之间似乎有明确的关系。总的来说,无论含水量如何,体积比随着压力的增加而增加。总的来说,在用二氧化碳进行的实验中,数据表明含水量会影响膨胀率,但最终的体积比保持不变。这项工作的结果很重要,因为它们表明了w/ho乳液的相行为,并且CO2和CH4可以根据系统中油和水的组成变化很大。IFT、相对体积和PVT测量提供了建立流体模型所需的关键信息,以减少油藏模拟和历史匹配中的不确定性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Underlying physics of heavy oil recovery by gas injection: An experimental parametric analysis when oil exists in the form of oil based emulsion
Heavy oil in reservoirs exists in the form of either water in heavy oil (w/ho) emulsions after primary production under water drive, or during secondary recovery methods such as water or steam injection. In many cases, the decision to apply any secondary or tertiary methods such as CO2 or CH4 injection depends on the understanding of the behavior of these gases in w/ho emulsions at reservoir conditions. Such an understanding can reduce the uncertainties in reservoir modeling by providing an adequate fluid model for reservoir simulation and history matching studies. In this paper, we focus on the interfacial properties, relative volume change, and PVT behavior of CO2 and CH4 in (w/ho) emulsions. We first generated the (w/ho) emulsion using steam at 150oC. Next, the stability of our emulsion was tested using different criteria such as phase separation, viscosity of the produced emulsion compared with that of the starting oil, and the size and number of water droplets in the continuous medium. The experiments were run using two types of heavy oils that are collected from two representative fields in eastern Alberta, type A oil (27,000 cP) and type B oil (4,351 cP). A sensitivity analysis was performed to determine the impact of different operational variables such as water content in the emulsion, water pH, and flow rate; additionally, the role of asphaltene and resin in emulsion stability was investigated. The influence of water content in the emulsion was found to be critical and thus subsequent IFT and relative volume measurements as well as PVT analyses were conducted using emulsions of different water contents with a vol.% range from 10-70. The results were compared with a dead oil (no water) case. Two types of gases typically used to improve recovery in Alberta were tested: CO2 and CH4. IFT and volume measurements indicate the existence of critical water content which dramatically changes the behavior of the system; generally, emulsions with water content below this critical value exhibit lower IFT than the original oil, and the IFT falls steadily as the water content increases. The trend is reversed when the water content exceeds the critical value and IFT starts increasing before it stabilizes. This process happens when the water content reaches a vol.% higher than 50; however, it remains below that of the original oil. Regarding volume ratio, there seems to be a clear relationship between pressure and volume ratio of the emulsion and CO2 system. Overall, volume ratio increases as pressure increases regardless of water content. In general, for experiments run with CO2, data suggests that water content affects the rate of expansion, but ultimately the final volume ratio remains the same. The results of this work are significant in that they indicate the phase behavior of w/ho emulsions, and that CO2 and CH4 can vary considerably depending on the composition of oil and water content in the system. IFT, relative volume, and PVT measurements provide key information needed to build an adequate fluid model to reduce the uncertainties in reservoir simulation and history matching.
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