高熵合金Cantor CoCrFeMnNi的力学性能控制

V. Gromov, S. Konovalov, Yu. A. Shlyarova, M. Efimov, I. Panchenko
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摘要

简要分析了各种改变高能合金(HEA) Cantor CoCrFeMnNi力学性能的方法。介绍了铝、钒、锰、钛、硅、碳、铜合金化对真空电弧熔炼、激光熔炼、电弧熔炼和滴铸、机械合金化后等离子烧结、气体溅射后冲击波和静态压实等风力涡轮机硬化的影响。结果表明,添加2.5% TiC和5% WC显著提高了合金的抗拉强度,但降低了断裂伸长率。4.4 ~ 155µm的晶粒尺寸对拉伸强度的影响是随晶粒尺寸的减小而增大。降低温度可提高各种尺寸晶粒的强度和屈服极限。强化塑性变形形成纳米级(~50 nm)晶粒,显著提高抗拉强度至1950 MPa,硬度达520 HV。随后的等时和等温退火允许改变风力涡轮机的强度和延展性。在冲击复合、机械合金化和随后的火花等离子体形成过程中,纳米结构相状态的形成显著提高了室温下的抗拉强度,保持了优异的塑性(伸长率约为28%)。电子束处理(electronic -beam processing, EPO)是改善风力发电机力学性能的方法之一。对采用线弧增材制造技术获得的风力机在电子束能量密度为10 ~ 30 J/cm2的EPO后的变形曲线进行了分析;关于强度和延性降低的原因的假设已经被发现和证实。对各种方法得到的康托风力机力学性能进行了对比分析,指出了强度和塑性参数值存在差异的原因。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Control of mechanical properties of a high-entropy alloy Cantor CoCrFeMnNi
A brief analysis of the work on changing the mechanical properties of the high-energy alloy (HEA) Cantor CoCrFeMnNi in various ways has been performed. The article describes the influence of alloying with aluminum, vanadium, manganese, titanium, silicon, carbon, copper on the hardening of wind turbines obtained by vacuum arc melting, laser melting, arc melting and drip casting, mechanical alloying with subsequent plasma sintering, gas sputtering followed by shock wave and static compaction. It is shown that additives of 2.5 % TiC and 5 % WC significantly improve the tensile strength, but reduce the elongation to failure. The effect of grain size in the range of 4.4 – 155 µm is to increase the tensile strength with a decrease in grain size. Lowering the temperature increases the strength and yield limits for grains of all sizes. Intensive plastic deformation forming nanoscale (~50 nm) grains significantly increases the tensile strength up to 1950 MPa and hardness up to 520 HV. Subsequent isochronous and isothermal annealing allows varying the strength and ductility of wind turbines. The formation of nanostructured-phase states during shock compounding, mechanical alloying and subsequent spark plasma formation significantly increase the tensile strength at room temperature, maintaining excellent plasticity (elongation of approximately 28 %). As one of the methods of modifying the mechanical properties of wind turbines, the authors propose electron-beam processing (EPO). The analysis of the deformation curves of the wind turbine, obtained by the technology of wire-arc additive production, after EPO with an electron beam energy density of 10 – 30 J/cm2, has been carried out; assumptions about the reasons for the decrease in strength and ductility characteristics have been found and substantiated. A comparative analysis of mechanical properties of the Cantor wind turbine obtained by various methods was carried out, and the reasons for discrepancy in the values of strength and plastic parameters were noted.
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