热压法制备铝铬系陶瓷

T. Sata, R. Kiyoura
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引用次数: 1

摘要

含20至70 vol. % Cr的铝铬陶瓷体在1400°-1470°C和150kg/cm2下在氩气中热压20-30分钟,使用直径为8mm的圆孔或4×15mm的矩形孔的石墨模具。研究结果表明:(1)在热压过程中,随着铬含量的增加,压坯温度降低,如铬含量为60vol . %时,压坯温度为1400°~ 1430°C,比氢气气氛下的热压温度低300°C左右(表1)。(2)测量了热压体沿中线的硬度分布。研究了比例为2:1的压紧方法,采用柱塞在浮模中向下移动的压紧方式,得到了最佳的压紧效果。(表2和图3)。(3)对形状复杂的热压体的硬度分布进行了研究,发现由于混合物流动性不足,存在硬度值较低的区域;(4)在室温下,尺寸为4×4×15mm的热压体的横向断裂强度为55 ~ 72kg/mm2。(5)热压体的显微结构特点是出现了1 ~ 3μ量级的小刚玉晶体,氧化铝和铬相之间的边界比氢气氛烧结体更粗糙。在铬含量大于60-70 vol. %的热压体中观察到连续的金属相(图3)。(6)弯曲断裂试验试样的拉伸侧断口通过晶体。因此,在电子显微照片中同时出现了铬和刚玉相(图4-5)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Fabricating the Cermet of the System Alumina-Chromium by Hot Pressing
Alumina-chromium cermet bodies containing 20 to 70 vol. % Cr were hot-pressed at 1400°-1470°C and 150kg/cm2 for 20-30 min., in argon atmosphere using graphite molds having a circular hole of 8mm in diameter, or a rectangular hole of 4×15mm.From the results of this study it was concluded that:(1) In hot pressing, increase in the chromium content decreased the press-temperature, for instance, 1400°-1430°C for 60 vol. % of chromium, being about 300°C lower than the hot-pressing temperature in hydrogen atomosphere (Table 1).(2) Measuring the hardness distribution along the center line of hot-pressed bodies whose hight to dia. ratio was 2:1 the method of pressing was studied, and the best result was obtained when the pressure was applied with a plunger moving downwards in a floating die. (Table 2 and Fig. 3).(3) The distribution of hardness in hot-pressed bodies of complex shape was studied with a result that there are some regions giving lower hardness values caused by the lack of the flowability of the mix, which suggests the necessity of three directional pressing (Photo. 2).(4) The transverse rupture strength of hot-pressed bodies of the size 4×4×15mm were 55-72kg/mm2 at room temperature.(5) The microstructure of hot-pressed bodies was characterized by the occurence of smaller corundum crystals of the order 1-3μ, and by the more rough boundaries between the alumina and chromium phase than those in the bodies sintered in hydrogen atmosphere. Continuous metallic phase was observed in the hot-pressed bodies containing more chromium than 60-70 vol. % (Photo. 3).(6) Fractures in the tension side of the specimens of bending rupture test passed through the crystals. of corundum, chromium as well as their phase boundary, and consequently, both chromium and corundum phases were appeared in the electron microphotographs (Photo. 4-5).
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