基于金属配体策略的Pd6(RuL3)8纳米菱形十二面体金属-有机笼的逐步组装及其对客体的捕获和保护

IF 15.6 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of the American Chemical Society Pub Date : 2014-03-10 DOI:10.1021/ja410044r

Kang Li, Lu-Yin Zhang, Cheng Yan, Shi-Chao Wei, Mei Pan*, Li Zhang, Cheng-Yong Su*

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引用次数: 220

摘要

逐步合成纳米Pd?描述了由预先设计的氧化还原和光活性Ru(II)-金属配体和裸Pd(II)离子组成的Ru异核金属有机笼。所得到的笼形为菱形十二面体，包含一个5350 ?3的腔和12个开窗，有助于有效捕获极性和非极性客体分子。研究了光敏客体对紫外线辐射的保护。

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Stepwise Assembly of Pd6(RuL3)8 Nanoscale Rhombododecahedral Metal–Organic Cages via Metalloligand Strategy for Guest Trapping and Protection

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Stepwise Assembly of Pd6(RuL3)8 Nanoscale Rhombododecahedral Metal–Organic Cages via Metalloligand Strategy for Guest Trapping and Protection

Stepwise synthesis of nanosized Pd?Ru heteronuclear metal–organic cages from predesigned redox- and photo-active Ru(II)-metalloligand and naked Pd(II) ion is described. The resulting cage shows rhombododecahedral shape and contains a 5350 ?³ cavity and 12 open windows, facilitating effective trapping of both polar and nonpolar guest molecules. Protection of photosensitive guests against UV radiation is studied.

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来源期刊

Journal of the American Chemical Society 化学-化学综合

CiteScore

24.40

自引率

6.00%

发文量

2398

审稿时长

1.6 months

期刊介绍： The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.