{"title":"猴面包果果肉和种子甲醇提取物在1.0 M H2SO4中对低碳钢的缓蚀和吸附行为","authors":"P. Karungamye, H. Murthy","doi":"10.9790/5736-1007016474","DOIUrl":null,"url":null,"abstract":"Abstract : Adansonia digitata (Baobab) pulp and seeds extracts have been tested for corrosion inhibition of mild steel in 1.0 M H2SO4 solution at room temperature. The inhibition efficiency and corrosion rate were studied using gravimetric, polarization and electrochemical impedance spectroscopy (EIS) methods. The surface morphology of MS was studied with scanning electron microscope (SEM). The Results revealed that Adansonia digitata seeds extract (ADSE) was found to be better corrosion inhibitor for mild steel in H2SO4 than Adansonia digitata pulp extracts (ADPE). Inhibition efficiency was found to be 57.65% and 68.70% for ADPE and ADSE respectively. Polarization studies revealed that both ADPE and ADSE act as mixed-type inhibitor. Adsorption isotherm was found using experimental data obtained in weight loss measurements. The absorption of both extracts on the mild steel surface was found to follow Langmuir adsorption isotherm. The surface analysis using scanning electron microscopy (SEM) confirmed both ADPE and ADSE played a significant protective effect on mild steel in1.0 M H2SO4 solution. ADPE and ADSE could serve as effective green inhibitors for mild steel corrosion in 1.0 M H2SO4 solution due to the adsorption of phytoconstituents of extracts.","PeriodicalId":14488,"journal":{"name":"IOSR Journal of Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2017-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Corrosion Inhibitive and Adsorption Behaviour of Methanolic Extracts of Adansonia digitata (Baobab) Fruit Pulp and Seeds for Mild Steel in 1.0 M H2SO4\",\"authors\":\"P. Karungamye, H. Murthy\",\"doi\":\"10.9790/5736-1007016474\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract : Adansonia digitata (Baobab) pulp and seeds extracts have been tested for corrosion inhibition of mild steel in 1.0 M H2SO4 solution at room temperature. The inhibition efficiency and corrosion rate were studied using gravimetric, polarization and electrochemical impedance spectroscopy (EIS) methods. The surface morphology of MS was studied with scanning electron microscope (SEM). The Results revealed that Adansonia digitata seeds extract (ADSE) was found to be better corrosion inhibitor for mild steel in H2SO4 than Adansonia digitata pulp extracts (ADPE). Inhibition efficiency was found to be 57.65% and 68.70% for ADPE and ADSE respectively. Polarization studies revealed that both ADPE and ADSE act as mixed-type inhibitor. Adsorption isotherm was found using experimental data obtained in weight loss measurements. The absorption of both extracts on the mild steel surface was found to follow Langmuir adsorption isotherm. The surface analysis using scanning electron microscopy (SEM) confirmed both ADPE and ADSE played a significant protective effect on mild steel in1.0 M H2SO4 solution. ADPE and ADSE could serve as effective green inhibitors for mild steel corrosion in 1.0 M H2SO4 solution due to the adsorption of phytoconstituents of extracts.\",\"PeriodicalId\":14488,\"journal\":{\"name\":\"IOSR Journal of Applied Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2017-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IOSR Journal of Applied Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.9790/5736-1007016474\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IOSR Journal of Applied Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.9790/5736-1007016474","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
摘要
摘要:研究了猴面包树(Adansonia digitata, Baobab)果肉和种子提取物在1.0 M H2SO4溶液中对低碳钢的缓蚀作用。采用重量法、极化法和电化学阻抗谱(EIS)研究了其缓蚀效率和腐蚀速率。用扫描电镜(SEM)研究了质谱的表面形貌。结果表明,ADSE在H2SO4中对低碳钢的缓蚀性能优于ADPE。对ADPE和ADSE的抑制率分别为57.65%和68.70%。极化研究表明ADPE和ADSE均为混合型抑制剂。吸附等温线是利用失重测量得到的实验数据得到的。两种提取物在低碳钢表面的吸附均遵循Langmuir吸附等温线。扫描电镜(SEM)表面分析证实,在1.0 M H2SO4溶液中,ADPE和ADSE对低碳钢均有显著的保护作用。在1.0 M H2SO4溶液中,ADPE和ADSE对其提取物中的植物成分有吸附作用,可作为有效的缓蚀剂。
Corrosion Inhibitive and Adsorption Behaviour of Methanolic Extracts of Adansonia digitata (Baobab) Fruit Pulp and Seeds for Mild Steel in 1.0 M H2SO4
Abstract : Adansonia digitata (Baobab) pulp and seeds extracts have been tested for corrosion inhibition of mild steel in 1.0 M H2SO4 solution at room temperature. The inhibition efficiency and corrosion rate were studied using gravimetric, polarization and electrochemical impedance spectroscopy (EIS) methods. The surface morphology of MS was studied with scanning electron microscope (SEM). The Results revealed that Adansonia digitata seeds extract (ADSE) was found to be better corrosion inhibitor for mild steel in H2SO4 than Adansonia digitata pulp extracts (ADPE). Inhibition efficiency was found to be 57.65% and 68.70% for ADPE and ADSE respectively. Polarization studies revealed that both ADPE and ADSE act as mixed-type inhibitor. Adsorption isotherm was found using experimental data obtained in weight loss measurements. The absorption of both extracts on the mild steel surface was found to follow Langmuir adsorption isotherm. The surface analysis using scanning electron microscopy (SEM) confirmed both ADPE and ADSE played a significant protective effect on mild steel in1.0 M H2SO4 solution. ADPE and ADSE could serve as effective green inhibitors for mild steel corrosion in 1.0 M H2SO4 solution due to the adsorption of phytoconstituents of extracts.