F. Majoumo-Mbe, Irene N. Mukoko, D. T. Nde, O. Offiong, E. Nfor
{"title":"2-乙酰吡啶N(4)乙基硫代氨基脲锰配合物的合成、晶体及分子结构","authors":"F. Majoumo-Mbe, Irene N. Mukoko, D. T. Nde, O. Offiong, E. Nfor","doi":"10.21060/CIS.V4I1.2305","DOIUrl":null,"url":null,"abstract":"A novel Mn(II) complex with thiosemicarbazone derived from 2-acetylpyridine and N(4)-ethylthiosemicarbazide has been prepared. The single-crystal X-ray analysis of the Mn(II) complex showed a distorted octahedral MnN 4 S 2 environment with the ligand chelating via the nitrogen and sulfur donor atoms in a tridentate manner. The triclinic form of the ligand which has crystallized in a monoclinic system in other works is also described. The basicity of nitrogen atoms of the ligand was tested with its reaction with HNO 3 and the structure of the salt obtained is reported. The result shows that the lone pair of the pyridine nitrogen is more available due to the delocalization of other nitrogen lone pair of electron. http://dx.doi.org/10.21060/cis.2016.411","PeriodicalId":10648,"journal":{"name":"Communications in Inorganic Synthesis","volume":"51 1","pages":"5-11"},"PeriodicalIF":0.0000,"publicationDate":"2016-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Synthesis, crystal and molecular structure of manganese (II) complex of 2-acetylpyridine N (4) ethylthiosemicarbazone\",\"authors\":\"F. Majoumo-Mbe, Irene N. Mukoko, D. T. Nde, O. Offiong, E. Nfor\",\"doi\":\"10.21060/CIS.V4I1.2305\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A novel Mn(II) complex with thiosemicarbazone derived from 2-acetylpyridine and N(4)-ethylthiosemicarbazide has been prepared. The single-crystal X-ray analysis of the Mn(II) complex showed a distorted octahedral MnN 4 S 2 environment with the ligand chelating via the nitrogen and sulfur donor atoms in a tridentate manner. The triclinic form of the ligand which has crystallized in a monoclinic system in other works is also described. The basicity of nitrogen atoms of the ligand was tested with its reaction with HNO 3 and the structure of the salt obtained is reported. The result shows that the lone pair of the pyridine nitrogen is more available due to the delocalization of other nitrogen lone pair of electron. http://dx.doi.org/10.21060/cis.2016.411\",\"PeriodicalId\":10648,\"journal\":{\"name\":\"Communications in Inorganic Synthesis\",\"volume\":\"51 1\",\"pages\":\"5-11\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-03-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Communications in Inorganic Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.21060/CIS.V4I1.2305\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Communications in Inorganic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21060/CIS.V4I1.2305","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis, crystal and molecular structure of manganese (II) complex of 2-acetylpyridine N (4) ethylthiosemicarbazone
A novel Mn(II) complex with thiosemicarbazone derived from 2-acetylpyridine and N(4)-ethylthiosemicarbazide has been prepared. The single-crystal X-ray analysis of the Mn(II) complex showed a distorted octahedral MnN 4 S 2 environment with the ligand chelating via the nitrogen and sulfur donor atoms in a tridentate manner. The triclinic form of the ligand which has crystallized in a monoclinic system in other works is also described. The basicity of nitrogen atoms of the ligand was tested with its reaction with HNO 3 and the structure of the salt obtained is reported. The result shows that the lone pair of the pyridine nitrogen is more available due to the delocalization of other nitrogen lone pair of electron. http://dx.doi.org/10.21060/cis.2016.411
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
