Z. Fan, Yu Yin, Qiyang Tan, Xuliang Li, P. Niu, Rui-di Li, Tiechui Yuan, Mingxing Zhang, Han Huang
{"title":"揭示激光3d打印al2o3 - zro - 2共晶陶瓷的凝固模式转变和晶体学特征","authors":"Z. Fan, Yu Yin, Qiyang Tan, Xuliang Li, P. Niu, Rui-di Li, Tiechui Yuan, Mingxing Zhang, Han Huang","doi":"10.2139/ssrn.3939456","DOIUrl":null,"url":null,"abstract":"The crystallographic texture distribution in 3D-printed Al2O3-ZrO2 eutectics was found completely different from those prepared by directional solidification. The as-fabricated specimen was mainly composed of randomly oriented eutectic colonies, as a result of the initial uncoupled growth at molten pool boundaries. Specifically, the free-grown Al2O3 faceted particulates in the uncoupled region acted as effective nucleation sites that triggered coupled eutectic renucleation and growth. Except for some misoriented ZrO2 precipitates in Al2O3 matrix, well-defined multiple crystallographic orientation relationships existed between eutectic phases in the colony, e.g. {0001}Al2O3 ∥ {100}ZrO2 and {1120}Al2O3∥ {100}ZrO2. The lattice matching change was attributed to the varied solidification conditions along the solid/liquid interface, as predicted by Jackson-Hunt model.","PeriodicalId":7765,"journal":{"name":"AMI: Scripta Materialia","volume":"67 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Unveiling Solidification Mode Transition and Crystallographic Characteristics in Laser 3D-Printed Al 2O 3-ZrO 2 Eutectic Ceramics\",\"authors\":\"Z. Fan, Yu Yin, Qiyang Tan, Xuliang Li, P. Niu, Rui-di Li, Tiechui Yuan, Mingxing Zhang, Han Huang\",\"doi\":\"10.2139/ssrn.3939456\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The crystallographic texture distribution in 3D-printed Al2O3-ZrO2 eutectics was found completely different from those prepared by directional solidification. The as-fabricated specimen was mainly composed of randomly oriented eutectic colonies, as a result of the initial uncoupled growth at molten pool boundaries. Specifically, the free-grown Al2O3 faceted particulates in the uncoupled region acted as effective nucleation sites that triggered coupled eutectic renucleation and growth. Except for some misoriented ZrO2 precipitates in Al2O3 matrix, well-defined multiple crystallographic orientation relationships existed between eutectic phases in the colony, e.g. {0001}Al2O3 ∥ {100}ZrO2 and {1120}Al2O3∥ {100}ZrO2. The lattice matching change was attributed to the varied solidification conditions along the solid/liquid interface, as predicted by Jackson-Hunt model.\",\"PeriodicalId\":7765,\"journal\":{\"name\":\"AMI: Scripta Materialia\",\"volume\":\"67 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"AMI: Scripta Materialia\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2139/ssrn.3939456\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"AMI: Scripta Materialia","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2139/ssrn.3939456","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Unveiling Solidification Mode Transition and Crystallographic Characteristics in Laser 3D-Printed Al 2O 3-ZrO 2 Eutectic Ceramics
The crystallographic texture distribution in 3D-printed Al2O3-ZrO2 eutectics was found completely different from those prepared by directional solidification. The as-fabricated specimen was mainly composed of randomly oriented eutectic colonies, as a result of the initial uncoupled growth at molten pool boundaries. Specifically, the free-grown Al2O3 faceted particulates in the uncoupled region acted as effective nucleation sites that triggered coupled eutectic renucleation and growth. Except for some misoriented ZrO2 precipitates in Al2O3 matrix, well-defined multiple crystallographic orientation relationships existed between eutectic phases in the colony, e.g. {0001}Al2O3 ∥ {100}ZrO2 and {1120}Al2O3∥ {100}ZrO2. The lattice matching change was attributed to the varied solidification conditions along the solid/liquid interface, as predicted by Jackson-Hunt model.