B. Zoheir, A. Holzheid, A. Zeh, R. McAleer, Mohamed El-Behairy, U. Schwarz-Schampera, T. Graupner, D. Lentz, F. Xiong
{"title":"埃及Sukari金矿床:地球化学和年代学对矿石成因的制约及对区域找矿的指示意义","authors":"B. Zoheir, A. Holzheid, A. Zeh, R. McAleer, Mohamed El-Behairy, U. Schwarz-Schampera, T. Graupner, D. Lentz, F. Xiong","doi":"10.5382/econgeo.4990","DOIUrl":null,"url":null,"abstract":"\n The Sukari gold deposit (>15 Moz Au) in the Eastern Desert of Egypt is hosted by a deformed granitoid stock (Sukari tonalite-trondhjemite intrusion) and mainly occurs as a network of crosscutting sulfide-bearing quartz (± carbonate) veins and intensely sulfidized-silicified-sericitized wall rock. Emplacement of the Sukari intrusion into a tectonized Neoproterozoic accretionary complex was controlled by a system of NE- to NNE-trending oblique faults that are related to a deep-seated positive flower structure. A robust genetic model has been hampered by the poorly understood relationships between gold mineralization and host rocks. In this study, zircon U-Pb ages of three samples from the Sukari intrusion define a crystallization age of ~695 ± 2 Ma. In contrast, hydrothermal sericite from the ore zone yields an 40Ar/39Ar age of ~625 ± 3 Ma, which coincides with the onset of major sinistral transpression in the region.\n Features including sigmoidal morphology of gold quartz veins and abundant subhorizontal tension gashes alongside widespread brecciation and recrystallization suggest that quartz veining occurred during renewed shortening and exhumation through the brittle-ductile transition. Petrographic and micro-X-ray fluorescence (µXRF) studies indicate that disseminated gold and sulfides, commonly associated with sericite and carbonate alteration, are mostly confined to stylolitic bands in the quartz veins. Oscillatory and sector zoning patterns, irregular As-rich bands, and truncations between early- and late-genetic pyrites reflect variations in temperature and mechanism of ore deposition, demonstrated by variable As/S and Co/Ni ratios in the different pyrite generations. Laser ablation-inductively coupled plasma-mass spectrometry analysis pinpoints the covariance of gold and arsenic contents in pyrite, but free milling gold inclusions in microfractures consistently have a mercury-bearing electrum composition, depicting different ore formation stages.\n Ore fluids with δ34SH2s values of –1.9 to –3.0‰, modeled from gold-associated pyrite and arsenopyrite assemblages with nearly identical δ34S values, suggest a likely single source of sulfur. Alternatively, multisourced sulfur could have extensively mixed and equilibrated by fluid reaction with carbonaceous wall rock. Gold deposition was triggered by abrupt changes in fluid pH and fO2. As an implication for future exploration, sites of maximized strain gradients adjacent to granitoid bodies along extensive transpression zones in the district could be highly prospective targets, particularly where imprinted by sericite-carbonate ± graphite alteration.","PeriodicalId":11469,"journal":{"name":"Economic Geology","volume":"28 1","pages":""},"PeriodicalIF":5.5000,"publicationDate":"2022-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The Sukari Gold Deposit, Egypt: Geochemical and Geochronological Constraints on the Ore Genesis and Implications for Regional Exploration\",\"authors\":\"B. Zoheir, A. Holzheid, A. Zeh, R. McAleer, Mohamed El-Behairy, U. Schwarz-Schampera, T. Graupner, D. Lentz, F. Xiong\",\"doi\":\"10.5382/econgeo.4990\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n The Sukari gold deposit (>15 Moz Au) in the Eastern Desert of Egypt is hosted by a deformed granitoid stock (Sukari tonalite-trondhjemite intrusion) and mainly occurs as a network of crosscutting sulfide-bearing quartz (± carbonate) veins and intensely sulfidized-silicified-sericitized wall rock. Emplacement of the Sukari intrusion into a tectonized Neoproterozoic accretionary complex was controlled by a system of NE- to NNE-trending oblique faults that are related to a deep-seated positive flower structure. A robust genetic model has been hampered by the poorly understood relationships between gold mineralization and host rocks. In this study, zircon U-Pb ages of three samples from the Sukari intrusion define a crystallization age of ~695 ± 2 Ma. In contrast, hydrothermal sericite from the ore zone yields an 40Ar/39Ar age of ~625 ± 3 Ma, which coincides with the onset of major sinistral transpression in the region.\\n Features including sigmoidal morphology of gold quartz veins and abundant subhorizontal tension gashes alongside widespread brecciation and recrystallization suggest that quartz veining occurred during renewed shortening and exhumation through the brittle-ductile transition. Petrographic and micro-X-ray fluorescence (µXRF) studies indicate that disseminated gold and sulfides, commonly associated with sericite and carbonate alteration, are mostly confined to stylolitic bands in the quartz veins. Oscillatory and sector zoning patterns, irregular As-rich bands, and truncations between early- and late-genetic pyrites reflect variations in temperature and mechanism of ore deposition, demonstrated by variable As/S and Co/Ni ratios in the different pyrite generations. Laser ablation-inductively coupled plasma-mass spectrometry analysis pinpoints the covariance of gold and arsenic contents in pyrite, but free milling gold inclusions in microfractures consistently have a mercury-bearing electrum composition, depicting different ore formation stages.\\n Ore fluids with δ34SH2s values of –1.9 to –3.0‰, modeled from gold-associated pyrite and arsenopyrite assemblages with nearly identical δ34S values, suggest a likely single source of sulfur. Alternatively, multisourced sulfur could have extensively mixed and equilibrated by fluid reaction with carbonaceous wall rock. Gold deposition was triggered by abrupt changes in fluid pH and fO2. 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The Sukari Gold Deposit, Egypt: Geochemical and Geochronological Constraints on the Ore Genesis and Implications for Regional Exploration
The Sukari gold deposit (>15 Moz Au) in the Eastern Desert of Egypt is hosted by a deformed granitoid stock (Sukari tonalite-trondhjemite intrusion) and mainly occurs as a network of crosscutting sulfide-bearing quartz (± carbonate) veins and intensely sulfidized-silicified-sericitized wall rock. Emplacement of the Sukari intrusion into a tectonized Neoproterozoic accretionary complex was controlled by a system of NE- to NNE-trending oblique faults that are related to a deep-seated positive flower structure. A robust genetic model has been hampered by the poorly understood relationships between gold mineralization and host rocks. In this study, zircon U-Pb ages of three samples from the Sukari intrusion define a crystallization age of ~695 ± 2 Ma. In contrast, hydrothermal sericite from the ore zone yields an 40Ar/39Ar age of ~625 ± 3 Ma, which coincides with the onset of major sinistral transpression in the region.
Features including sigmoidal morphology of gold quartz veins and abundant subhorizontal tension gashes alongside widespread brecciation and recrystallization suggest that quartz veining occurred during renewed shortening and exhumation through the brittle-ductile transition. Petrographic and micro-X-ray fluorescence (µXRF) studies indicate that disseminated gold and sulfides, commonly associated with sericite and carbonate alteration, are mostly confined to stylolitic bands in the quartz veins. Oscillatory and sector zoning patterns, irregular As-rich bands, and truncations between early- and late-genetic pyrites reflect variations in temperature and mechanism of ore deposition, demonstrated by variable As/S and Co/Ni ratios in the different pyrite generations. Laser ablation-inductively coupled plasma-mass spectrometry analysis pinpoints the covariance of gold and arsenic contents in pyrite, but free milling gold inclusions in microfractures consistently have a mercury-bearing electrum composition, depicting different ore formation stages.
Ore fluids with δ34SH2s values of –1.9 to –3.0‰, modeled from gold-associated pyrite and arsenopyrite assemblages with nearly identical δ34S values, suggest a likely single source of sulfur. Alternatively, multisourced sulfur could have extensively mixed and equilibrated by fluid reaction with carbonaceous wall rock. Gold deposition was triggered by abrupt changes in fluid pH and fO2. As an implication for future exploration, sites of maximized strain gradients adjacent to granitoid bodies along extensive transpression zones in the district could be highly prospective targets, particularly where imprinted by sericite-carbonate ± graphite alteration.
期刊介绍:
The journal, now published semi-quarterly, was first published in 1905 by the Economic Geology Publishing Company (PUBCO), a not-for-profit company established for the purpose of publishing a periodical devoted to economic geology. On the founding of SEG in 1920, a cooperative arrangement between PUBCO and SEG made the journal the official organ of the Society, and PUBCO agreed to carry the Society''s name on the front cover under the heading "Bulletin of the Society of Economic Geologists". PUBCO and SEG continued to operate as cooperating but separate entities until 2001, when the Board of Directors of PUBCO and the Council of SEG, by unanimous consent, approved a formal agreement of merger. The former activities of the PUBCO Board of Directors are now carried out by a Publications Board, a new self-governing unit within SEG.