从可再生的不可食用农业废弃物中开发防水耐热蒙脱土改性高压胶合板——“烧瓶-反应器”工艺的工业案例研究

M. Akram, M. Asad, S. M. Zehra, A. Farooq, A. Mahmood, M. Arfan, S. T. Hussain Shah
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引用次数: 0

摘要

可持续发展模式要求产品合成从“烧瓶到反应器”的经济过渡,这需要大学、工业和资助机构之间的同步。在我们的实验室里,我们已经成功地开发了一种原型方法来合成粘接酚醛树脂,从甘蔗的提取物中提取的生物质残渣作为胶合板样品的填充材料。本设计方法具有无剩余废料的优点。通过在胶合板中浸渍官能化蒙脱土,提高了胶合板的防水性能、耐热性能和机械强度。随后,在中试工厂规模上(Saccharum munja)从农业残留物中开发出了耐水防火木复合材料(MDF)。以中试工厂为原料,从农用废渣(糖蜜和花生)中提取绿色前体糠醛(树脂/胶水合成用)。合成了有机官能化粘土,并在树脂(酚醛-糠醛)制备过程中掺入有机官能化粘土。以糠醛提取后的植物为原料,利用植物残渣和树脂热压制备木质复合材料(MDF)。对木复合材料的原型产品进行了表征和评价,并进行了防火和防水分析。结果表明,制备的样品具有良好的耐火和防水性能。该产品将成为木质复合材料市场的一个很好的候选人,并且是绿色环保的。用于树脂合成的糠醛是致癌物质甲醛的潜在替代品,甲醛主要用于木材复合材料和胶合板工业。巴基斯坦是一个农业国家,拥有丰富的矿藏。幸运的是,本项目所需的原材料,如可再生生物质,包括农业残留物和不可食用植物,以及矿物,如蒙脱土,都有充足的供应。因此,这个项目很有可能开发出具有成本效益和质量改进的胶合板产品,这些产品适销对路,可以产生正现金流。TTSF平台被用来支持学术界(HEC & NUST)和工业界(KDC Boards (Pvt) Ltd, Woodworld (Pvt) Ltd和TASCO Mines (LLP))之间有前途的伙伴关系,以促进大学开发的技术研究向工业和商业部门的转移。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Development of Waterproof Cum Heat Resistant, Montmorillonite Clay Modified High- Pressure Plywood Composite from Renewable-Nonedible Agricultural Wastes – An Industrial Case Study of ‘Flask to Reactor’ Approach
A sustainable development model demands an economical transition of product synthesis from ‘Flask to Reactor,’ which demands synchronization between universities, industries and funding agencies. In our lab, we have successfully developed a prototype method for synthesizing adhesive phenol-furfural resin from extracts of Saccharum munja while biomass residues of this feedstock extraction were employed as filling materials for manufacturing plywood samples. This designed method has the advantage of no leftover waste material. Moreover, waterproofing, heat resistance and mechanical strength were improved by impregnating functionalized montmorillonite clay into these prepared plywood samples. Subsequently, water and fire-resistant wood composite (MDF) was developed from agricultural residue on a pilot plant scale ( Saccharum munja ). Green precursor furfural (for resin/glue synthesis) was extracted from agricultural residue (Saccharum munja and peanut plant) on a pilot plant scale. Organic functionalization clay was also synthesized and incorporated during resin (Phenol-Furfural) preparation. Plant materials left after furfural extraction were further used for wood composite (MDF) preparation by hot pressing of plant residue and resin. Characterization and evaluation of prototype wood composite products were also performed for fire and waterproof analysis. Results have shown that prepared samples have good fire and water-resistant activities. This product will be a good candidate for the wood composite market and is green. Furfural, used for resin synthesis, is a potential replacement for carcinogenic formaldehyde, which is largely used in wood composite and plywood industries. Pakistan is an agricultural country and is enriched with mineral reservoirs. Fortunately, raw materials required for this project, i.e. renewable biomass including agricultural residue and nonedible plants, and minerals, i.e. montmorillonite clay, are available in ample quantities. Thus, this project has good potential to develop cost-effective and improved quality plywood products that are marketable and can generate positive cash flow. TTSF platform was employed to support promising partnerships between academia (HEC & NUST) and industry (KDC Boards (Pvt) Ltd, Woodworld (Pvt) Ltd & TASCO Mines (LLP)) to facilitate the transfer of university-developed technological research to industry and the commercial sector.
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