LDPE、LLDPE、MDPE和HDPE型聚乙烯混合料水解解聚所得重切削油的表征

Dr.Gautam Kumar Roy
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引用次数: 0

摘要

聚乙烯废弃物已成为世界范围内的主要污染物之一。将聚乙烯废料转化为有用的碳氢化合物产品正在进行研究和探索。对LDPE、LLDPE、MDPE和HDPE型聚乙烯进行加氢热解转化成烃产品。该产品包括气态产品和液态产品。该液体或母液产品由石脑油、中间馏分油和各种特性的重质油组成。重切削馏分是母液中以半液体馏分酸盐形式存在的部分。重切馏分是常压分馏法难以提取的馏分。因此,这部分保持在精馏塔的底部。研究了重质切削油的特性,发现它产生的结构具有较高的分子量,不易挥发,这是很重要的。从聚乙烯混合物中提取的重切油温度大于370℃,进行了模拟蒸馏分析和质谱分析,以了解重切油的热化学和结构性质或最终用途。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Characterization of the Heavy Cut Oil Extracted from the Hydropyrolytic Depolymerization of LDPE, LLDPE, MDPE and HDPE type of Polyethylene Mix
polyethylene waste has become one of the major pollutant worldwide. The conversion of the polyethylene waste into useful hydrocarbon products is being studied and investigated. The conversion of the LDPE, LLDPE, MDPE and HDPE type of polyethylene into hydrocarbon products via hydropyrolysis process is carried out. The product comprises of the gaseous and the liquid products. The liquid or the mother liquid product comprises of the naphtha, middle distillate and the heavy cut oil of varied characteristics. The heavy cut fraction is the part of the mother liquid which remains as the semi liquid fractionate. The heavy cut fraction is the part which is difficult to extract by the fractional distillation under atmospheric pressure. Thus this part remains at the bottom of the distillation column. The characteristic property of the heavy cut oil is studied and it is found to be important as it generates a structure with a higher molecular weight that is less easily volatilized.The heavy cut oil extracted from polyethylene mix has temperature grater than 370 C. Simulated distillation analysis and the mass spectra analysis were carried out to understand the thermo chemical and the structural properties of the heavy cut oil or end use.
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