用物理化学方法研究离子液体在不同纤维素溶液中的溶解行为

Ashutosh Dutta, Kanak Roy, S. Basak, Sukdev Majumder, M. Roy
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引用次数: 7

摘要

通过电解电导率、密度(η)和FT-IR光谱研究了1,3 -二甲基咪唑甲基硫酸酯(IL)和一些不同工业上重要的烷氧醇或纤维素溶液的溶液行为。用傅氏电导方程计算了在电导、密度和粘度的条件下离子的极限摩尔电导(Λ0)、缔合常数(KA)、最接近距离(R)等参数。从热力学参数的角度讨论了分子相互作用的定量值,包括一些非共价相互作用。讨论了纯溶剂的官能团和离子液体在不同溶剂中的结构特征,并对其进行了光谱学研究。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation of Solution Behaviour of an Ionic Liquid in Diverse Cellosolves by Physicochemical Contrivance
Solution behaviour prevailing in 1, 3-dimethylimidazoliummethylsulfate (IL) and some diverse industrially important alkoxy-alcohols or cellosolves have been investigated by electrolytic conductivity, density (⍴), viscosity (η) and FT-IR spectroscopic investigation. The derived parameters such as the limiting molar conductivities (Λ0), association constants (KA), the distance of closest approach (R), etc. of the ions supplemented with conductance, density and viscosity have been evaluated using the Fuoss conductance equation. The quantitative values of molecular interactions from thermodynamic parameters have been discussed in terms of some non-covalent interactions. Functional groups of the pure solvents and structural characteristics of ionic liquid in different solvents have been discussed and taken into contemplation for spectroscopic study.
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