{"title":"基于“鱼饵”捕获模式的新型水合肼传感器","authors":"Yaping He, Kexin Zhang, Xinchu Li, Q. Han, Yanyan Huo, Xiaohui Yang, Changhu Zhang","doi":"10.1080/10667857.2023.2190231","DOIUrl":null,"url":null,"abstract":"ABSTRACT Coordination reaction is a usual way for the concentration of metal ions in aqueous solution. In this work, 5-(5-iodine-2-pyridine azo)-2,2 amie toluene (5-PADAT) was firstly casting onto carbon glass electrode (GCE), play a role of ‘bait’; then, immersed 5-PADAT modified GCE into immersed aqueous solution containing order of magnitude ppm Palladium ions (Pd2+, play a role of ‘fishes’); ‘Fishes’ were captured by ‘bait’ with the reaction process of 5-PADAT and Pd2+, leading to the concentration of Pd2+ onto the GCE; Cyclic voltammetry was employed to reduce Pd2+ in situ, formed Pd nanoparticles (PdNPs) modified GCE. It can be used to detect the oxidation of hydrazine hydrate at a very low potential, 0.1 V.","PeriodicalId":18270,"journal":{"name":"Materials Technology","volume":"38 1","pages":""},"PeriodicalIF":2.9000,"publicationDate":"2023-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Novel hydrazine hydrate sensor based on”fish-bait” capture mode\",\"authors\":\"Yaping He, Kexin Zhang, Xinchu Li, Q. Han, Yanyan Huo, Xiaohui Yang, Changhu Zhang\",\"doi\":\"10.1080/10667857.2023.2190231\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT Coordination reaction is a usual way for the concentration of metal ions in aqueous solution. In this work, 5-(5-iodine-2-pyridine azo)-2,2 amie toluene (5-PADAT) was firstly casting onto carbon glass electrode (GCE), play a role of ‘bait’; then, immersed 5-PADAT modified GCE into immersed aqueous solution containing order of magnitude ppm Palladium ions (Pd2+, play a role of ‘fishes’); ‘Fishes’ were captured by ‘bait’ with the reaction process of 5-PADAT and Pd2+, leading to the concentration of Pd2+ onto the GCE; Cyclic voltammetry was employed to reduce Pd2+ in situ, formed Pd nanoparticles (PdNPs) modified GCE. It can be used to detect the oxidation of hydrazine hydrate at a very low potential, 0.1 V.\",\"PeriodicalId\":18270,\"journal\":{\"name\":\"Materials Technology\",\"volume\":\"38 1\",\"pages\":\"\"},\"PeriodicalIF\":2.9000,\"publicationDate\":\"2023-03-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1080/10667857.2023.2190231\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Technology","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1080/10667857.2023.2190231","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Novel hydrazine hydrate sensor based on”fish-bait” capture mode
ABSTRACT Coordination reaction is a usual way for the concentration of metal ions in aqueous solution. In this work, 5-(5-iodine-2-pyridine azo)-2,2 amie toluene (5-PADAT) was firstly casting onto carbon glass electrode (GCE), play a role of ‘bait’; then, immersed 5-PADAT modified GCE into immersed aqueous solution containing order of magnitude ppm Palladium ions (Pd2+, play a role of ‘fishes’); ‘Fishes’ were captured by ‘bait’ with the reaction process of 5-PADAT and Pd2+, leading to the concentration of Pd2+ onto the GCE; Cyclic voltammetry was employed to reduce Pd2+ in situ, formed Pd nanoparticles (PdNPs) modified GCE. It can be used to detect the oxidation of hydrazine hydrate at a very low potential, 0.1 V.
期刊介绍:
Materials Technology: Advanced Performance Materials provides an international medium for the communication of progress in the field of functional materials (advanced materials in which composition, structure and surface are functionalised to confer specific, applications-oriented properties). The focus is on materials for biomedical, electronic, photonic and energy applications. Contributions should address the physical, chemical, or engineering sciences that underpin the design and application of these materials. The scientific and engineering aspects may include processing and structural characterisation from the micro- to nanoscale to achieve specific functionality.