{"title":"含单金属-碳键的金属配合物的一些性质","authors":"H. Hill, J. M. Pratt, ROBERT J. P. Williams","doi":"10.1039/DF9694700165","DOIUrl":null,"url":null,"abstract":"The physical and chemical properties, including electronic absorption, infra-red, and 1H n.m.r. spectra of cobalt(III) complexes of the type CoA4XY, where A4 can be corrin, a Schiffs base, or dimethylglyoxime and X a carbon ligand, are discussed in terms of the change in electron density in the complex. It is shown that alkyl ligands act as strong donors, often giving rise to five-co-ordinate complexes. The relationship of the properties of these five-co-ordinate cobalt(III) complexes to those of analogous cobalt(II) nickel(II) and palladium(II) complexes is discussed and the difference between the cobalt-carbon bond in the five- and six-co-ordinate complexes considered.","PeriodicalId":11262,"journal":{"name":"Discussions of The Faraday Society","volume":"28 1","pages":"165-171"},"PeriodicalIF":0.0000,"publicationDate":"1969-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"22","resultStr":"{\"title\":\"Some properties of metal complexes containing one metal-carbon bond\",\"authors\":\"H. Hill, J. M. Pratt, ROBERT J. P. Williams\",\"doi\":\"10.1039/DF9694700165\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The physical and chemical properties, including electronic absorption, infra-red, and 1H n.m.r. spectra of cobalt(III) complexes of the type CoA4XY, where A4 can be corrin, a Schiffs base, or dimethylglyoxime and X a carbon ligand, are discussed in terms of the change in electron density in the complex. It is shown that alkyl ligands act as strong donors, often giving rise to five-co-ordinate complexes. The relationship of the properties of these five-co-ordinate cobalt(III) complexes to those of analogous cobalt(II) nickel(II) and palladium(II) complexes is discussed and the difference between the cobalt-carbon bond in the five- and six-co-ordinate complexes considered.\",\"PeriodicalId\":11262,\"journal\":{\"name\":\"Discussions of The Faraday Society\",\"volume\":\"28 1\",\"pages\":\"165-171\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1969-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"22\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Discussions of The Faraday Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/DF9694700165\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Discussions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/DF9694700165","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Some properties of metal complexes containing one metal-carbon bond
The physical and chemical properties, including electronic absorption, infra-red, and 1H n.m.r. spectra of cobalt(III) complexes of the type CoA4XY, where A4 can be corrin, a Schiffs base, or dimethylglyoxime and X a carbon ligand, are discussed in terms of the change in electron density in the complex. It is shown that alkyl ligands act as strong donors, often giving rise to five-co-ordinate complexes. The relationship of the properties of these five-co-ordinate cobalt(III) complexes to those of analogous cobalt(II) nickel(II) and palladium(II) complexes is discussed and the difference between the cobalt-carbon bond in the five- and six-co-ordinate complexes considered.