117号元素的发现(特邀)

J. Roberto
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引用次数: 0

摘要

2016年11月,四种新的化学元素nihonium (Nh, Z=113)、moscovium (Mc, Z=115)、tennessine (Ts, Z=117)和oganesson (Og, Z=118)加入了元素周期表。元素117和118是迄今为止Z达到的最高原子序数,而这些元素的A=294同位素是迄今为止合成的最重的原子核。这些元素的存在,以及随着中子数N的增加,超重同位素寿命持续增加的趋势,为超重核在N=184处接近核壳闭合时寻求已久的“稳定岛”提供了强有力的证据。Mc、Ts和Og是在俄罗斯联合核研究所的杜布纳气体填充反冲分离器上,利用热聚变过程用强束双重神奇的Ca离子轰击锕系元素目标时发现的。对于117号元素,需要一个来自橡树岭国家实验室(ORNL)的锫靶。这些锫是在ORNL的高通量同位素反应堆中通过强中子辐照产生的,并在毗邻的放射化学工程开发中心进行化学分离。Bk + Ca反应产生117号元素的两种同位素,原子量分别为A=293和294。这些同位素衰变为元素115、113、111、109、107和105的另外10个最重的同位素,它们都比以前所预测的稳定岛更接近。117号元素的发现将与最近超重元素研究中其他实验的结果一起在锕系元素靶材料的关键重要性,对元素周期表和稳定岛的影响,以及合成更重原子核的机会的背景下进行描述,包括118号元素的重同位素和新元素119和120。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The discovery of element 117 (INVITED)
In November 2016, four new chemical elements, nihonium (Nh, Z=113), moscovium (Mc, Z=115), tennessine (Ts, Z=117), and oganesson (Og, Z=118) joined the periodic table. Elements 117 and 118 are the highest atomic numbers Z reached to date, and the A=294 isotopes of these elements are the heaviest nuclei ever synthesized. The existence of these elements, together with a consistent trend of increasing lifetimes for superheavy isotopes as neutron number N increases, provide strong evidence for the long sought “island of stability” for superheavy nuclei as the nuclear shell closure at N=184 is approached. Mc, Ts, and Og were discovered using the hot fusion process, bombarding actinide targets with intense beams of doubly-magic Ca ions at the Dubna Gas-Filled Recoil Separator at the Joint Institute for Nuclear Research in Russia. For element 117, a berkelium target from Oak Ridge National Laboratory (ORNL) was required. The berkelium was produced by intense neutron irradiation at ORNL’s High Flux Isotope Reactor and chemically separated at the adjoining Radiochemical Engineering Development Center. The Bk + Ca reaction produced two isotopes of element 117 with atomic weights A=293 and 294. These isotopes decayed into ten additional heaviest isotopes of elements 115, 113, 111, 109, 107, and 105, all closer to the predicted island of stability than previously achieved. The discovery of element 117 will be described together with results of other recent experiments in superheavy element research in the context of the critical importance of actinide target materials, implications for the periodic table and the island of stability, and opportunities to synthesize even heavier nuclei, including heavy isotopes of element 118 and new elements 119 and 120.
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